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Diethyl 2-bromoethylphosphonate

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Diethyl 2-bromoethylphosphonate Basic information
Product Name:Diethyl 2-bromoethylphosphonate
Synonyms:DIETHYL 2-BROMOETHANEPHOSPHONATE;Diethyl2-bromoethylphosphonate,97%;2-BROMOETHYLPHOSPHONIC ACID DIETHYL ESTER;Diethyl bromoethylphosphonate;NSC 119421;NSC 2672;O,O-Diethyl (2-bromoethyl)phosphonate;DIETHYL 2-BROMOETHYLPHOSPHOTE
CAS:5324-30-1
MF:C6H14BrO3P
MW:245.05
EINECS:226-193-3
Product Categories:Horner-Emmons Reaction;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction;C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:5324-30-1.mol
Diethyl 2-bromoethylphosphonate Structure
Diethyl 2-bromoethylphosphonate Chemical Properties
Boiling point 75 °C/1 mmHg (lit.)
density 1.348 g/mL at 25 °C (lit.)
refractive index n20/D 1.461(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
form Liquid
Specific Gravity1.2751.348
color Clear colorless to slightly yellow
Water Solubility Soluble in water(20 g/L) (25°C).
BRN 1766077
InChIInChI=1S/C6H14BrO3P/c1-3-9-11(8,6-5-7)10-4-2/h3-6H2,1-2H3
InChIKeyPINITSMLVXAASM-UHFFFAOYSA-N
SMILESP(CCBr)(=O)(OCC)OCC
CAS DataBase Reference5324-30-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 23-24/25
WGK Germany 3
HS Code 29319090
Storage Class10 - Combustible liquids
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Diethyl 2-bromoethylphosphonate Usage And Synthesis
Chemical Propertiesclear colorless to slightly yellow liquid
UsesIt is employed as a reactant involved in radical coupling, synthesis of organosoluble zirconium phosphonate nanocomposites, click-chemistry, asymmetric epoxidation of unfunctionalized olefins, Negishi alkyl-aryl cross-coupling, and in synthesis of hydrolytically stable phosphonic acids for use as dental adhesives.
reaction suitabilityreaction type: C-C Bond Formation
Tag:Diethyl 2-bromoethylphosphonate(5324-30-1) Related Product Information
Dimethyl ethylphosphonite Diethyl ethylphosphonate Diethyl 2-bromoethylphosphonate Ethylphosphonic acid Methylphosphonic acid Diethyl phosphite Diethyl methylphosphonate Hypophosphorous acid Dimethyl methylphosphonate Phosphine Phosphorus Dimethyl phosphite Methyldiethoxyphosphine Phosphorous acid Ethyl methylphosphonic acid Diethyl phosphate Dimethyl ethylphosphonate Ethyl hydrogen ethylphosphonate