[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE

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Products Intro: Product Name:[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
CAS:127593-28-6
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Products Intro: Product Name:[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
CAS:127593-28-6
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Products Intro: Product Name:[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
CAS:127593-28-6
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Products Intro: Product Name:[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE
CAS:127593-28-6
Purity:98%，pd>13.3% Package:5g,50g,100g,250g,500g,1kg,5kg
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Products Intro: Product Name:Dichloro[(S)-()-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II)
CAS:127593-28-6
Purity:99%min Package:100g/bottle;500g/bottle;1kg/bottle;10kg/drum;50kg/drum;100kg/drum;5296T/drum;

[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE manufacturers
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Basic information
Uses Reaction
Product Name:[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE
Synonyms:[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)CHLORIDE;PALLADIUM, [(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYLBIS[DIPHENYLPHOSPHINE-.KAPPA.P]]DICHLORO-, (SP-4-2)-;REF DUPL: [(S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium (II) chloride;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II), min. 98%;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),Min.98%;Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]palladiuM(II),98% (S-BINAP)PdCl2;2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYLPALLADIUM(II) CHLORIDE;[(S)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II)
CAS:127593-28-6
MF:C44H34Cl2P2Pd
MW:802.02
EINECS:631-388-5
Product Categories:Pd
Mol File:127593-28-6.mol
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Structure
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Chemical Properties
Melting point >300°C
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
AppearanceLight yellow to yellow Solid
InChIKeyVDHAUMFISVWIRX-UHFFFAOYSA-L
SMILES[Cl-][Pd+2]1(P(C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC3=CC=CC=C3C=2C2C3=CC=CC=C3C=CC=2P1(C1C=CC=CC=1)C1C=CC=CC=1)[Cl-]
CAS DataBase Reference127593-28-6
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
MSDS Information
ProviderLanguage
SigmaAldrich English
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Usage And Synthesis
Uses[(S)-(-)-2,2-bis(diphenylphosphine)-1,1-binaphthyl]palladium dichloride is an organometallic derivative that can be used as a noble metal catalyst.
Reaction
  1. Catalyst precursor, with AgBF4 , for the enantioselective addition of silyl ethers, to imines to produce β-amino ketones, and to aldehydes to produce 3-hydroxy-1-propanone aldol addition products.
  2. Catalyst precursor, with AgSbF6, for the asymmetric carbonyl-ene reaction.
  3. Catalyst precursor for hetero Diels-Alder reaction of simple dienes with aldehydes and aryl glyoxals.
Reactions of 127593-28-6
[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE Preparation Products And Raw materials
Tag:[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]PALLADIUM(II) CHLORIDE(127593-28-6) Related Product Information
Dichloro[(S)-(-)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II) Dichloro[(R)-(+)-2,2’-bis(diphenylphosphino)-1,1-binaphthyl]paltinum(II) [(R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]palladium(II) chloride DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1S,2S)-(-)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL][(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM (II) DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl