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2,6-Dimethylphenylmagnesium bromide

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2,6-Dimethylphenylmagnesium bromide manufacturers

2,6-Dimethylphenylmagnesium bromide Basic information
Product Name:2,6-Dimethylphenylmagnesium bromide
Synonyms:2,6-Dimethylphenylmagnesium bromide solution;2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE, 1.0 M SOLUTION IN TETRAHYDROFURAN;2,6-Dimethylphenylmagnesium bromide solution 1.0 in THF;2,6-DiMethylphenylMagnesiuM broMide, 0.5M in 2-MeTHF;2,6-Dimethylphenylmagnesium bromide, 0.5 M in THF;2,6-DiMethylphenylMagnesiuM broMide, 1M solution in THF, AcroSeal;2,6-Dimethylphenylmagnesium bromide solution 1.0 M in THF;Magnesium,bromo(2,6-dimethylphenyl)-
CAS:21450-64-6
MF:C8H9BrMg
MW:209.37
EINECS:
Product Categories:Grignard Reagent;Aryl;Grignard Reagents;Organometallic Reagents;Chemical Synthesis;Grignard Reagents;Organometallic Reagents
Mol File:21450-64-6.mol
2,6-Dimethylphenylmagnesium bromide Structure
2,6-Dimethylphenylmagnesium bromide Chemical Properties
Boiling point 65-67 °C
density 0.998 g/mL at 25 °C
Fp −2 °F
form Solution
color Colorless to yellow-brown
Sensitive Air & Moisture Sensitive
InChI1S/C8H9.BrH.Mg/c1-7-4-3-5-8(2)6-7;;/h3-5H,1-2H3;1H;/q;;+1/p-1
InChIKeyBIGUVDUZGAJWQK-UHFFFAOYSA-M
SMILESCc1cccc(C)c1[Mg]Br
CAS DataBase Reference21450-64-6
Safety Information
Hazard Codes F,C
Risk Statements 11-14-19-20/21/22-34-40-37-14/15
Safety Statements 16-23-26-36/37/39-45-43
RIDADR UN 3399 4.3/PG 2
WGK Germany 3
HazardClass 3
Storage Class4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard ClassificationsAcute Tox. 3 Inhalation
Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 2
MSDS Information
ProviderLanguage
SigmaAldrich English
2,6-Dimethylphenylmagnesium bromide Usage And Synthesis
Uses2,6-Dimethylphenylmagnesium bromide can be used:
  • As an intermediate in the synthesis of dibutyl(5,10-dihydro-1,9-di-p-toluoyl-5-p-tolyldipyrrinato)tin(IV), which is further used in the preparation of zinc-based porphyrin.
  • As a substrate in the preparation of substituted fluorenes by reacting with 2-substituted arenesulfonates and dihaloarenes.

reaction suitabilityreaction type: Grignard Reaction
2,6-Dimethylphenylmagnesium bromide Preparation Products And Raw materials
Tag:2,6-Dimethylphenylmagnesium bromide(21450-64-6) Related Product Information
3 5-Dimethyoxyphenylmagnesium chloride 4-Fluoro-3-methylphenylmagnesium bromide 1-Propenylmagnesium bromide 4-Fluorophenylmagnesium bromide Phenylmagnesium bromide 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex Hexylmagnesium chloride 1-PROPYNYLMAGNESIUM BROMIDE 2-BUTENYLMAGNESIUM CHLORIDE 2-METHOXYPHENYLMAGNESIUM BROMIDE 3-BUTENYLMAGNESIUM BROMIDE M-TOLYLMAGNESIUM BROMIDE 3-FLUOROPHENYLMAGNESIUM BROMIDE 2,4,6-Trimethylphenylmagnesium bromide 2,3,5,6-Tetramethylphenylmagnesium bromide 2,3,4,5,6-PENTAMETHYLPHENYLMAGNESIUM BROMIDE 4-TERT-BUTYL-2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE 2,6-DIMETHYLPHENYLMAGNESIUM BROMIDE