- 9-bbn triflate
-
- $1.10
-
2026-08-25
- CAS:62731-43-5
- Min. Order: 1kg
- Purity: 99%min
- Supply Ability: 100kg
- 9-BBN TRIFLATE
-
- $1.00
-
2019-07-10
- CAS:62731-43-5
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 25kg
|
| | 9-BBN triflate Basic information |
| Product Name: | 9-BBN triflate | | Synonyms: | 9-BORABICYCLO[3.3.1]NONYL TRIFLUOROMETHANESULFONATE;9-bbn triflate solution;9-borabicyclo(3.3.1)nonanyl trifluoromethanesulphonate;9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution;9-BBN TRIFLATE, 0.5M SOLUTION IN HEXANES;9-BBN TRIFLATE SOLUTION, ~0.5 M IN HEXAN E;9-BBN triflate solution, 9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate solution;9-Borabicyclo[3.3.1]nonyl trifluoromethanesulfonate, 0.5M solution in diethyl ether, AcroSeal | | CAS: | 62731-43-5 | | MF: | C9H14BF3O3S | | MW: | 270.08 | | EINECS: | | | Product Categories: | | | Mol File: | 62731-43-5.mol |  |
| | 9-BBN triflate Chemical Properties |
| Boiling point | 265.7±50.0 °C(Predicted) | | density | 0.733 g/mL at 25 °C | | Fp | -22 °C | | solubility | sol common inert organic solvents such as Et2O, CH2Cl2, and hexane. | | form | liquid | | BRN | 995656 | | InChI | 1S/C9H14BF3O3S/c11-9(12,13)17(14,15)16-10-7-3-1-4-8(10)6-2-5-7/h7-8H,1-6H2/t7-,8+ | | InChIKey | NXHUKDCGEGEZCX-OCAPTIKFSA-N | | SMILES | FC(F)(F)S(=O)(=O)OB1C2CCCC1CCC2 |
| | 9-BBN triflate Usage And Synthesis |
| Uses | Reactant for:
- Preparation of a dialkylborenium ion stabilized by an N-heterocyclic carbene
- Mukaiyama aldol addition
- Preparation of porphyrin dimethyldioxanyl tolyl derivative complex
- Preparation of palladium porphyrin complexes
- Boron-mediated β-alkoxy Me ketone aldol addition reactions
| | Application | 9-Bbn triflate can be used to prepare Lewis acids of vinyloxyboranes and boryl nitrify salts; a catalyst for the coupling of silyl enol ethers and acetals; and a catalyst for the isomerization of epoxides to allyl alcohols. | | Preparation | Equimolar amounts of 9-Borabicyclo[3.3.1]nonane and Trifluoromethanesulfonic Acid are mixed in hexane and stirred at 20 °C for 24 h after which time 9-BBN TRIFLATE is isolated by vacuum distillation. | | reaction suitability | reagent type: reductant | | storage | Use in a fume hood; the neat liquid as well as solutions are moisture and air sensitive; therefore the material should be stored and transferred under a dry inert atmosphere. |
| | 9-BBN triflate Preparation Products And Raw materials |
|