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| | Acetyltrimethylsilane Basic information |
| Product Name: | Acetyltrimethylsilane | | Synonyms: | 1-(TRIMETHYLSILYL)ETHANONE;ACETYLTRIMETHYLSILAN;1-TRIMETHYLSILANYL-ETHANONE;Acetyltrimethylsilane,1-(Trimethylsilyl)ethanone;Silane,acetyltrimethyl-;SKL041;Acetyltrimethylsilane | | CAS: | 13411-48-8 | | MF: | C5H12OSi | | MW: | 116.23 | | EINECS: | 220-404-2 | | Product Categories: | | | Mol File: | 13411-48-8.mol |  |
| | Acetyltrimethylsilane Chemical Properties |
| Melting point | <0°C | | Boiling point | 113-114°C | | density | 0.811 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.411(lit.) | | Fp | 48 °F | | storage temp. | 2-8°C | | Specific Gravity | 0.811 | | Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions | | BRN | 2071361 | | InChI | 1S/C5H12OSi/c1-5(6)7(2,3)4/h1-4H3 | | InChIKey | REDWSDBFBCDPNI-UHFFFAOYSA-N | | SMILES | CC(=O)[Si](C)(C)C |
| Hazard Codes | F,Xi | | Risk Statements | 11-36/37/38 | | Safety Statements | 16-26-36 | | RIDADR | UN 1993 3/PG 2 | | WGK Germany | 3 | | F | 8-10-21 | | TSCA | No | | HazardClass | 3.1 | | PackingGroup | II | | Storage Class | 3 - Flammable liquids | | Hazard Classifications | Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2
STOT SE 3 |
| | Acetyltrimethylsilane Usage And Synthesis |
| Uses | Acetyltrimethylsilane can be used as a reagent in the synthesis of dihydrophenanthrenes via a C-C insertion reaction. It is also used as a source of carbanion in the synthesis of unsymmetrical biaryls by carbanion-induced ring transformation of 2H-pyran-2-ones under mild basic conditions. |
| | Acetyltrimethylsilane Preparation Products And Raw materials |
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