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Chlorobis(cyclooctene)rhodium(I) dimer

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Products Intro: Product Name:Chlorobis(cyclooctene)rhodium(I) dimer
CAS:12279-09-3
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CAS:12279-09-3
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Products Intro: Product Name:Chlorobis(cyclooctene)rhodium(I) dimer
CAS:12279-09-3
Package:1KG;5KG;25KG Remarks:yellow crystalline powder
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CAS:12279-09-3
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CAS:12279-09-3
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Chlorobis(cyclooctene)rhodium(I) dimer Basic information
Product Name:Chlorobis(cyclooctene)rhodium(I) dimer
Synonyms:[RhCl(cis-cyclooctene)2]2;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Chlorobis(cyclooctene)rhodium(I);Chlorobis(cyclooctene)rhodium(I)dimere;Chlorobis(cyclooctene)rhodium(I)dimer,min.98%;Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%;CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
CAS:12279-09-3
MF:C32H56Cl2Rh2
MW:717.5
EINECS:623-340-7
Product Categories:Rh;organometallic complex;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium;1
Mol File:12279-09-3.mol
Chlorobis(cyclooctene)rhodium(I) dimer Structure
Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties
Melting point 190 °C (dec.) (lit.)
storage temp. Freezer
form crystal
color orange to red
Optical Rotation-0.60°(C=0.01g/ml CHCL3)
Sensitive air sensitive, store cold
InChI1S/4C8H14.2ClH.2Rh/c4*1-2-4-6-8-7-5-3-1;;;;/h4*1-2H,3-8H2;2*1H;;/q;;;;;;2*+1/p-2/b4*2-1-;;;;
InChIKeyGQPAPAIPOLEZHT-XFCUKONHSA-L
SMILESCl[Rh].Cl[Rh].C1CCCC=CCC1.C2CCCC=CCC2.C3CCCC=CCC3.C4CCCC=CCC4
CAS DataBase Reference12279-09-3
Safety Information
Hazard Codes Xn
Risk Statements 20/21/22-36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA No
HS Code 28439000
Storage Class11 - Combustible Solids
Hazard ClassificationsAcute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
Chlorobis(cyclooctene)rhodium(I) dimer Usage And Synthesis
Chemical Propertiesorange-brown powder
UsesChlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst:
  • To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds.
  • In direct C-arylation of N-unprotected indoles and pyrroles.
  • In the carboxylation of arenes via C-H bond activation.

UsesChlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.
reaction suitabilitycore: rhodium
reagent type: catalyst
Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials
Tag:Chlorobis(cyclooctene)rhodium(I) dimer(12279-09-3) Related Product Information
DILINOLEIC ACID Chlorobis(ethylene)rhodium (I) dimer POLYALUMINUM CHLORIDE Rhodium(III) Chloride POLYETHYLENE, CHLORINATED Rhodium methoxy(cyclooctadiene)rhodium(i) dimer Acetylacetonatobis(ethylene)rhodium(I) BIS(NORBORNADIENE)RHODIUM (I) TETRAFLUOROBORATE cis-Cyclooctene Chlorinated polyethylene water-proof rolled materials ALKYLKETENE DIMER CYCLOOCTENE Chlorobis(cyclooctene)rhodium(I) dimer