ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic rhodium >(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE

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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Suppliers list
Company Name: Capot Chemical Co.,Ltd.
Tel: +86-（0）57185586718 +86-13336195806
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Products Intro: Product Name:(?à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat
CAS:213343-65-8
Purity:97%min HPLC Package:100g;1kg;5kg,10kg,25kg,50kg
Company Name: Shaanxi Dideu Medichem Co. Ltd
Tel: +86-29-81139210 +86-17392587031
Email: 1059@dideu.com
Products Intro: Product Name:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I)tetrafluoroborate,97%
CAS:213343-65-8
Purity:99.00% Package:25kgs/Drum;200kgs/Drum Remarks:ISO 9001：2015 REACH Approved Manufacturer
Company Name: Aladdin Scientific
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Email: tp@aladdinsci.com
Products Intro: Product Name:(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
CAS:213343-65-8
Purity:>=98%(S,S)-Me-BPE-Rh Package:$114.9/100mg;$385.9/500mg;$1388.9/2g;Bulk package Remarks:98%(S,S)-Me-BPE-Rh
Company Name: Shanghai Hanhong Scientific Co., Ltd.
Tel: +undefined17612118332
Email: Lucky@hanhonggroup.com
Products Intro: Product Name:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
CAS:213343-65-8
Package:5KG;1KG;100kg;1000kg
Company Name: ABCR GmbH & CO. KG
Tel: 49 721 95061 0
Email: info@abcr.de
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(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Basic information
Reaction
Product Name:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
Synonyms:(+)-1,2-Bis[(2S,5S)-2,5-diMethylphospholano]ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate, 97%;(-)-1,2-Bis((2S,5S)-2,5-diMethylphospholano)ethane(1,5-cyclooctadiene)rhodiuM(I) tetrafluoroborate (S,S)-Me-BPE-Rh;(à)-Methyl 2-benzyloxycarbonylamino-2-(dimethoxyphosphinyl)acetat;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I)tetrafluoroborate,98+%(S,S)-Me-BPE-Rh;(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh;(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE,98+%(S,S)-ME-BPE-RH;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane
CAS:213343-65-8
MF:C22H40BF4P2Rh-
MW:556.21
EINECS:
Product Categories:Chiral Catalysts, Ligands, and Reagents;DuPhos/BPE;Privileged Ligands and Complexes;organometallic complex
Mol File:213343-65-8.mol
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Structure
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Chemical Properties
Melting point 152.2-156.3 °C
storage temp. 2-8°C, protect from light, stored under nitrogen
form Crystalline Powder
color Orange to red to brown
Sensitive air sensitive
InChIKeyCVUPEPGZCZHSOF-ASDDUFFSSA-N
SMILES[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C[C@H]2CC[C@H](C)P2CCP3[C@@H](C)CC[C@@H]3C
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 22-24/25-26
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Usage And Synthesis
ReactionThe DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Reactions of 213343-65-8
UsesDuPhos and BPE Ligands: Highly Efficient Privileged Ligands

Catalyst for:
  • Asymmetric hydrogenation
(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE Preparation Products And Raw materials
Tag:(-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE(213343-65-8) Related Product Information
1,3-CYCLOOCTADIENE (+)-1,2-BIS((2R,5R)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2R,5R)-2,5-DIPHENYLPHOSPHOLANO)ETHANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE(CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (-)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)ETHANE 1,2-BIS(DIETHYLPHOSPHINO)ETHANE