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(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine

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(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine Basic information
Product Name:(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine
Synonyms:(S)-(-)-1-(2-PYRROLIDINYLMETHYL)PIPERIDINE;(S)-(-)-1-METHYL-2-(1-PIPERIDINOMETHYL)PYRROLIDINE;(S)-1-METHYL-2-(PIPERIDINOMETHYL)PYRROLIDINE;(S)-(-)-1-[(1-METHYL-2-PYRROLIDINYL)METHYL]PIPERIDINE;(S)-1-[(1-METHYL-2-PYRROLIDINYL)METHYL]PIPERIDINE;(S)-1-[(1-Methyl-2-pyrrolidinyl)-methyl]-piperidin;Piperidine,1-[[(2S)-1-Methyl-2-pyrrolidinyl]Methyl]-;(S)-1-((1-Methylpyrrolidin-2-yl)Methyl)piperidine
CAS:84466-85-3
MF:C11H22N2
MW:182.31
EINECS:
Product Categories:Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:84466-85-3.mol
(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine Structure
(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine Chemical Properties
Boiling point 121-123 °C22 mm Hg(lit.)
density 0.909 g/mL at 25 °C(lit.)
refractive index n20/D 1.478(lit.)
Fp 220 °F
storage temp. Inert atmosphere,Room Temperature
pka10.39±0.40(Predicted)
form clear liquid
color Colorless to Light yellow to Light orange
Optical Rotation[α]20/D 69°, c = 0.5 in ethanol
BRN 4242955
InChI1S/C11H22N2/c1-12-7-5-6-11(12)10-13-8-3-2-4-9-13/h11H,2-10H2,1H3/t11-/m0/s1
InChIKeyVCVPSRADUBPOKJ-NSHDSACASA-N
SMILESCN1CCC[C@H]1CN2CCCCC2
CAS DataBase Reference84466-85-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26-36
WGK Germany 3
F 10-34
HS Code 29339900
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
MSDS Information
ProviderLanguage
SigmaAldrich English
(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine Usage And Synthesis
UsesUseful chiral ligand for catalytic asymmetric aldol reactions. Mukaiyama, T.
(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine Preparation Products And Raw materials
Tag:(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine(84466-85-3) Related Product Information
(S)-(-)-1-Methyl-2-(1-piperidinomethyl)pyrrolidine 2-Butylpyrrolidine 2-Pyrrolidineethanamine,1-methyl-,(2S)-(9CI) DIMETHYL-(2-PIPERIDIN-2-YL-ETHYL)-AMINE Calebassine 2-(2-Aminoethyl)-1-methylpyrrolidine