2-Cyanobenzylzinc bromide

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2-Cyanobenzylzinc bromide Basic information
Product Name:2-Cyanobenzylzinc bromide
Synonyms:2-CYANOBENZYLZINC BROMIDE, 0.5M SOLUTION IN TETRAHYDROFURAN;2-cyanobenzylzinc bromide solution;2-Cyanobenzylzinc bromide solution 0.5 in THF;(2-cyanobenzyl)zinc(II) broMide;2-Cyanobenzylzinc bromide solution 0.5M in THF;2-Cyanobenzylzinc bromide 0.5 M in Tetrahydrofuran;2-CyanobenzyL;Zinc, bromo[(2-cyanophenyl)methyl]-
CAS:199465-66-2
MF:C8H6BrNZn
MW:261.43
EINECS:
Product Categories:Alkyl;Organozinc Halides;Reike and Organozinc Reagents
Mol File:199465-66-2.mol
2-Cyanobenzylzinc bromide Structure
2-Cyanobenzylzinc bromide Chemical Properties
density 0.993 g/mL at 25 °C
Fp 1 °F
storage temp. 2-8°C
InChI1S/C8H6N.BrH.Zn/c1-7-4-2-3-5-8(7)6-9;;/h2-5H,1H2;1H;/q;;+1/p-1
InChIKeyLQRNYQAXNZETFP-UHFFFAOYSA-M
SMILESBr[Zn]Cc1ccccc1C#N
Safety Information
Hazard Codes F,Xn
Risk Statements 14-19-22-36/38-40-36/37-11
Safety Statements 16-26-33-36-36/37
RIDADR UN 2056 3/PG 2
WGK Germany 1
Storage Class3 - Flammable liquids
Hazard ClassificationsCarc. 2
Eye Irrit. 2
Flam. Liq. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
2-Cyanobenzylzinc bromide Usage And Synthesis
Uses2-Cyanobenzylzinc bromide can be used as a reactant:
  • In the metal-catalyzed Negishi cross-coupling reactions to prepare aryl or heteroaryl derivatives via carbon-carbon bond formation.
  • To synthesize 4-(2-Cyanobenzyl)-3′-(trifluoromethyl)biphenyl by reacting with aryl nonaflate in the presence of Pd(dba)2 as a catalyst.
  • To prepare 2-[(2-cyanophenyl)methyl] benzamide by treating with 2-iodobenzamide using a nickel catalyst.

2-Cyanobenzylzinc bromide Preparation Products And Raw materials
Tag:2-Cyanobenzylzinc bromide(199465-66-2) Related Product Information
Sodium cyanoborohydride 2-cyanopropionic acid 5-Nitroanthranilonitrile Benzylzinc bromide 2-Cyanobenzylzinc bromide