| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Email: |
saleschina@alfa-asia.com |
- ALLYL PHENYL SULFIDE
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- $1.00
-
2020-01-08
- CAS:5296-64-0
- Min. Order: 1KG
- Purity: 98%-99.9%
- Supply Ability: 200KG
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| | Allyl phenyl sulfide Basic information |
| | Allyl phenyl sulfide Chemical Properties |
| Melting point | -48--46.5 °C | | Boiling point | 223-225 °C(lit.) | | density | 1.024 g/mL at 20 °C(lit.) | | refractive index | n20/D 1.572 | | Fp | >98°C | | storage temp. | -20°C, stored under nitrogen | | solubility | insol water; sol most organic solvents | | form | clear liquid | | color | Colorless to Almost colorless | | Sensitive | Air Sensitive | | BRN | 1856940 | | InChI | 1S/C9H10S/c1-2-8-10-9-6-4-3-5-7-9/h2-7H,1,8H2 | | InChIKey | QGNRLAFFKKBSIM-UHFFFAOYSA-N | | SMILES | C=CCSc1ccccc1 | | LogP | 3.510 | | CAS DataBase Reference | 5296-64-0(CAS DataBase Reference) |
| Hazard Codes | Xn | | Risk Statements | 20/21 | | Safety Statements | 23-36/37/39 | | RIDADR | UN 2810 6.1/PG 2 | | WGK Germany | 3 | | RTECS | WR2400000 | | F | 13 | | HS Code | 2930.90.2900 | | HazardClass | 6.1(b) | | PackingGroup | III | | Storage Class | 6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | | Hazard Classifications | Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation |
| | Allyl phenyl sulfide Usage And Synthesis |
| Synthesis Reference(s) | Synthesis, p. 625, 1984
Tetrahedron, 47, p. 8621, 1991 DOI: 10.1016/S0040-4020(01)82405-4
Tetrahedron Letters, 20, p. 1481, 1979 | | Purification Methods | Dissolve the sulfide in Et2O, wash with alkali, H2O, dry over CaCl2, evaporate and fractionally distil it, preferably under vacuum. It should not give a precipitate with an alcoholic solution of Pb(OAc)2. [Hurd & Greengard J Am Chem Soc 52 3356 1930, Tarbell & McCall J Am Chem Soc 74 48 1952, Beilstein 6 IV 1479.] | | Preparation and handling | ALLYL PHENYL SULFIDE can be made from Allyl Bromide and sodium thiophenolate in ethanol.
Handling, Storage, and Precautions: must be handled in a fume hood due to stench caused by contamination with Thiophenol. The pure sulfide has a more agreeable odor with a sweet overtone. No special precautions are necessary when handling in the atmosphere for weighing and transferring. In order to avoid autoxidation the sulfide should be stored in a well sealed vessel with exclusion of oxygen and moisture at 4 °C. |
| | Allyl phenyl sulfide Preparation Products And Raw materials |
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