POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE manufacturers
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| | POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Basic information |
| | POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Chemical Properties |
| density | 0.913 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | Flammables + water-Freezer (-20°C)e area | | form | Solution | | color | Clear slightly yellow | | Sensitive | moisture sensitive | | InChI | InChI=1S/C12H25B.K/c1-7-10(4)13(11(5)8-2)12(6)9-3;/h13H,7-9H2,1-6H3;/q-1;+1 | | InChIKey | WRYQJJOHBLICCR-UHFFFAOYSA-N | | SMILES | [B+3]([H-])([C-](C)CC)([C-](C)CC)[C-](C)CC.[K+] | | EPA Substance Registry System | Borate(1-), hydrotris(1-methylpropyl)-, potassium, (T-4)- (54575-49-4) |
| Hazard Codes | F,C | | Risk Statements | 11-15-34-37-19-14/15-40 | | Safety Statements | 16-26-36/37/39-43-45 | | RIDADR | UN 3399 4.3/PG 1 | | WGK Germany | 3 | | F | 10 | | TSCA | TSCA listed | | HS Code | 29310099 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 1 |
| | POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Usage And Synthesis |
| Description | Potassium tri-sec-butylborohydride [54575- 49-4] solution in tetrahydrofuran (THF) is sold as K-Selectride (Aldrich). These compounds may be used for highly stereoselective reductions, e.g., of ketones . Chemical rearrangements induced by potassium hydride are important in organic chemistry. Furthermore, in combination with other reagents potassium hydride acts as a catalyst in the polymerization of alkenes and dienes. | | Chemical Properties | clear slightly yellow solution | | Uses | Reducing reagent. Reactant for: Preparation of a PCP-pincer palladium hydride-K-Selectride complex. Formation of P-H, P-C, and C-H bonds by hydride attack. Stereoselective conjugate hydride reduction reactions. | | Uses | Mild reducing agents in organic synthesis. | | Uses |
Reactant for:
- Preparation of a PCP-pincer palladium hydride-K-Selectride complex
- Formation of P-H, P-C, and C-H bonds by hydride attack
- Stereoselective conjugate hydride reduction reactions
| | reaction suitability | reagent type: reductant |
| | POTASSIUM TRI-SEC-BUTYLBOROHYDRIDE Preparation Products And Raw materials |
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