| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
| Company Name: |
Sigma-Aldrich |
| Tel: |
021-61415566 800-8193336 |
| Email: |
orderCN@merckgroup.com |
| Company Name: |
Alfa Chemistry |
| Tel: |
1-516-6625404 |
| Email: |
support@alfa-chemistry.com |
Potassium triethylborohydride manufacturers
|
| | Potassium triethylborohydride Basic information |
| Product Name: | Potassium triethylborohydride | | Synonyms: | potassiumtriethylborohydride,calselect?kt,;potassiumtriethylborohydride,calselect?kt,intetrahydrofuran;potassium triethylhydroborate;Potassium triethylborohydride, in tetrahydrofuran, 1M solution;POTASSIUM TRIETHYLBOROHYDRIDE, 1.0M SOLU TION IN TETRAHYDROFURAN;Potassiumtriethylborohydride,1.0MinTHF,inSure/Sealbottle;potassium triethylborohydride solution;POTASSIUM TRIETHYLBOROHYDRIDE, 1.0M IN THF, IN SURE/SEAL TM BOTTLE | | CAS: | 22560-21-0 | | MF: | C6H16BK | | MW: | 138.1 | | EINECS: | 245-077-3 | | Product Categories: | metal alkyl;Borohydrides;Reduction;Synthetic Reagents | | Mol File: | 22560-21-0.mol |  |
| | Potassium triethylborohydride Chemical Properties |
| density | 0.902 g/mL at 25 °C | | Fp | 1 °F | | storage temp. | Flammables + water-Freezer (-20°C)e area | | solubility | sol THF, diethyl ether, benzene, toluene. | | form | Solution | | color | Clear | | Sensitive | air sensitive, moisture sensitive | | InChI | 1S/C6H16B.K/c1-4-7(5-2)6-3;/h7H,4-6H2,1-3H3;/q-1;+1 | | InChIKey | MFRDRDKPANBWOI-UHFFFAOYSA-N | | SMILES | [K+].[H][B-](CC)(CC)CC |
| Hazard Codes | F,C | | Risk Statements | 11-14/15-19-20/21/22-34-37-40 | | Safety Statements | 16-26-27-36/37/39-45-43 | | RIDADR | UN 3399 4.3/PG 1 | | WGK Germany | 3 | | HS Code | 29310099 | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Acute Tox. 4 Oral
Carc. 2
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
Water-react 1 |
| | Potassium triethylborohydride Usage And Synthesis |
| Chemical Properties | CLEAR SOLUTION | | Uses | - Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity
- Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon
Reagent for:
- Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine
- Dehydrogenation reactions
- Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates
- Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons
- Substitution reactions
| | reaction suitability | reagent type: reductant | | Synthesis | Potassium Triethylborohydride is prepared by the reaction of Potassium Hydride with Triethylborane in THF, or benzene. From Potassium Triisopropoxyborohydride and triethylborane in THF and from sodium triethylborohydride and potassium amalgam in benzene. | | storage | The solution in THF is moisture- and air-sensitive, corrosive, and flammable. Reacts violently with water. Handle and store under nitrogen or argon in a cool place. Stable over prolonged periods of time. Use in a fume hood. Avoid contact with eyes, skin, and clothing. |
| | Potassium triethylborohydride Preparation Products And Raw materials |
|