Diethyl (ethylthiomethyl)phosphonate

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Diethyl (ethylthiomethyl)phosphonate Basic information
Product Name:Diethyl (ethylthiomethyl)phosphonate
Synonyms:DIETHYL ETHYLTHIOMETHANEPHOSPHONATE;NSC 140826;Diethyl (ethylthiomethyl)phosphonate 97%;1-[ethoxy(ethylsulfanylmethyl)phosphoryl]oxyethane;[(Ethylthio)methyl]phosphonic acid diethyl ester;Ethylthiomethylphosphonic acid diethyl ester;Phosphonic acid, P-[(ethylthio)methyl]-, diethyl ester;Diethyl (ethylthiomethyl)phosphonate
CAS:54091-78-0
MF:C7H17O3PS
MW:212.25
EINECS:258-971-3
Product Categories:C-C Bond Formation;Horner-Wadsworth-Emmons Reagents;Olefination
Mol File:54091-78-0.mol
Diethyl (ethylthiomethyl)phosphonate Structure
Diethyl (ethylthiomethyl)phosphonate Chemical Properties
Boiling point 127-127.5 °C(Press: 7 Torr)
density 1.097 g/mL at 25 °C(lit.)
refractive index n20/D 1.464(lit.)
Fp >230 °F
form liquid
InChI1S/C7H17O3PS/c1-4-9-11(8,10-5-2)7-12-6-3/h4-7H2,1-3H3
InChIKeyFTTKKJQNGIJGOC-UHFFFAOYSA-N
SMILESCCOP(=O)(CSCC)OCC
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
RIDADR UN 3334
WGK Germany 3
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
Diethyl (ethylthiomethyl)phosphonate Usage And Synthesis
UsesReactant for:
  • Preparation of spiro and fused N,O-heterocyclic phosphonate esters as antibacterial and antifungal agents
  • Preparation of spiro-substituted pyrimidine phosphonate esters as antitumor agents
  • Stereoselective Horner-Wadsworth-Emmons reactions
reaction suitabilityreaction type: C-C Bond Formation
Diethyl (ethylthiomethyl)phosphonate Preparation Products And Raw materials
Tag:Diethyl (ethylthiomethyl)phosphonate(54091-78-0) Related Product Information
Diethyl methylthiomethylphosphonate Diethyl (ethylthiomethyl)phosphonate Methyl methylphosphonic acid Ethyl methylphosphinate Ethyl methylphosphonic acid Methylphosphonic acid Dimethyl methylphosphonate Diethyl methylphosphonate Methyldiethoxyphosphine