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4-(Diphenylphosphino)benzoic acid

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Company Name: J & K SCIENTIFIC LTD.  
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4-(Diphenylphosphino)benzoic acid manufacturers

4-(Diphenylphosphino)benzoic acid Basic information
Product Name:4-(Diphenylphosphino)benzoic acid
Synonyms:Diphenyl(p-carboxyphenyl) phosphine;p-(Diphenylphosphino)benzoic acid;(4-Carboxyphenyl)diphenylphosphine;4-(Diphenylphosphino)benzoic acid 97%;4-di(phenyl)phosphanylbenzoic acid;4-Diphenylphosphanyl-benzoesaeure;4-(Diphenylphosphino)benzoic Acid >;Benzoic acid, 4-(diphenylphosphino)-
CAS:2129-31-9
MF:C19H15O2P
MW:306.3
EINECS:
Product Categories:Phosphine Ligands;Synthetic Organic Chemistry;Catalysis and Inorganic Chemistry;Phosphine Ligands;Phosphorus Compounds
Mol File:2129-31-9.mol
4-(Diphenylphosphino)benzoic acid Structure
4-(Diphenylphosphino)benzoic acid Chemical Properties
Melting point 157-160 °C (lit.)
Boiling point 448.0±28.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
pka4.01±0.10(Predicted)
form Crystalline Powder
color White to yellow
InChI1S/C19H15O2P/c20-19(21)15-11-13-18(14-12-15)22(16-7-3-1-4-8-16)17-9-5-2-6-10-17/h1-14H,(H,20,21)
InChIKeyGXMHDTPYKRTARV-UHFFFAOYSA-N
SMILESOC(=O)c1ccc(cc1)P(c2ccccc2)c3ccccc3
CAS DataBase Reference2129-31-9
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29163990
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
4-(Diphenylphosphino)benzoic acid Usage And Synthesis
Uses4-(Diphenylphosphino)benzoic acid can be used as a ligand in the synthesis of:
  • Organostannoxane-supported palladium nanoparticles. The resulting catalysts show high activity and selectivity in Suzuki-coupling reactions.
  • Polymetallic ruthenium-zinc complex catalyst for the hydrogenation of levulinic acid to γ-valerolactone.
reaction suitabilityreaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
4-(Diphenylphosphino)benzoic acid Preparation Products And Raw materials
Tag:4-(Diphenylphosphino)benzoic acid(2129-31-9) Related Product Information
1.1'-Binaphthyl-2.2'-diphemyl phosphine Diphenyl(p-tolyl)phosphine 4-Diphenylphosphanylbenzoic acid, 2-(trimethylsilyl)ethyl ester 4-(Diphenylphosphino)benzoic acid 2-(Diphenylphosphino)benzoic acid 2-(Diphenylphosphino)benzoic acid sodium salt 4-TOLYLPHOSPHINE Bis(4-carboxyphenyl)phenyl-phosphine oxide