(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline

(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Suppliers list
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(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Basic information
Product Name:(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline
Synonyms:(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline;1H-5,10b-Propano-1,7-phenanthroline, 2,3,4,4a,5,6-hexahydro-12-methyl-, (4aR,5S,10bR,12R)-;Lycodine
CAS:20316-18-1
MF:C16H22N2
MW:242.36
EINECS:
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Mol File:20316-18-1.mol
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Structure
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Chemical Properties
Melting point 118-119°
alpha D -10° (c = 1.01 in ethanol)
pka3.97, 8.08(at 25℃)
Safety Information
MSDS Information
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Usage And Synthesis
DescriptionOne of the numerous alkaloids obtained from the various Lycopodium species, this base has been found in L. annotinurn L. and L. fawcettii. It forms colourless crystals and has [α]D - 10° ± 2° (c 1.01, EtOH). One of the nitrogen atoms is present in a pyridine ring, the other being in the form of an imino group. The picrate is obtained as prisms from MeOH and has m.p. 229-233°C.
UsesLycodine is a lycopodium alkaloid, which can be isolated from Huperzia saururus. Lycodine exhibits anticholinesterase activity[1].
DefinitionChEBI: Lycodine is a phenanthrol.
ReferencesAnet, Eves., Can. J. Chern., 36,902 (1958)
Anet, Rao., Tetrahedron Lett., No. 20, 9 (1960)
Burnell et al., Can. J. Chern., 41, 3091 (1963)
(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline Preparation Products And Raw materials
Tag:(4aR,12R)-2,3,4,4aβ,5,6-Hexahydro-12-methyl-1H-5β,10bβ-propano-1,7-phenanthroline(20316-18-1) Related Product Information
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