S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine

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S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine Basic information
Product Name:S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine
Synonyms:S(-)-N,N-BIS(2-DIPHENYLPHOSPHINOETHYL)-ALPHA-METHYLBENZYLAMINE;(s)-(-)-n,n-bis(2-diphenylphosphinoethyl)-α-methylbenzylamine;Benzenemethanamine, N,N-bis[2-(diphenylphosphino)ethyl]-α-methyl-, (S)- (9CI);(S)-(?)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine;S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine
CAS:81510-19-2
MF:C36H37NP2
MW:545.63
EINECS:
Product Categories:
Mol File:81510-19-2.mol
S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine Structure
S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine Chemical Properties
Melting point 63-65 °C
Boiling point 632.8±45.0 °C(Predicted)
pka7.82±0.50(Predicted)
form solid
Optical Rotation[α]20/D 4.5±0.7°, c = 1% in acetone
BRN 4608384
InChIKeyZVNAHLJBPYKGBV-HKBQPEDESA-N
SMILESC[C@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 3259 8/PG 3
WGK Germany 3
1-10
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsEye Dam. 1
Skin Corr. 1B
MSDS Information
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SigmaAldrich English
S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine Usage And Synthesis
Uses(S)-(−)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.
General Description(S)-()-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.
S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine Preparation Products And Raw materials
Tag:S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine(81510-19-2) Related Product Information
R(+)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine S(-)-N,N-bis(2-diphenylphosphinoethyl)-1-phenylethylamine 2-(Diphenylphosphino)ethylamine