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Tetrakis(triphenylphosphine)platinum

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Tetrakis(triphenylphosphine)platinum manufacturers

Tetrakis(triphenylphosphine)platinum Basic information
Product Name:Tetrakis(triphenylphosphine)platinum
Synonyms:Tetrakis(triphenlphosphine) platinum;PLATINUM-TETRAKIS(TRIPHENYLPHOSPHINE);TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM;Tetrakis(triphenylphosphine)platinum(0),98%;( beta-4)-platinu;Tetrakis-(triphenylphosphino)-platinum;Tetrakis(triphenylphosphine)platinum(0), Pt 15.2% min;Platinum(0)tetrakis(triphenylphosphine)
CAS:14221-02-4
MF:C72H60P4Pt
MW:1244.219844
EINECS:238-087-4
Product Categories:Pt;metal-phosphine complexes
Mol File:14221-02-4.mol
Tetrakis(triphenylphosphine)platinum Structure
Tetrakis(triphenylphosphine)platinum Chemical Properties
Melting point 122 °C
storage temp. 2-8°C
solubility Soluble in benzene
form Liquid
color Clear
Water Solubility INSOLUBLE
Sensitive Air Sensitive
InChI1S/4C18H15P.Pt/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H;
InChIKeySYKXNRFLNZUGAJ-UHFFFAOYSA-N
SMILES[Pt].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12
CAS DataBase Reference14221-02-4(CAS DataBase Reference)
EPA Substance Registry SystemPlatinum, tetrakis(triphenylphosphine)-, (T-4)- (14221-02-4)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
8-10-23
TSCA TSCA listed
HS Code 29310099
Storage Class11 - Combustible Solids
MSDS Information
ProviderLanguage
Tetrakis(triphenylphosphine)platinum English
ACROS English
SigmaAldrich English
ALFA English
Tetrakis(triphenylphosphine)platinum Usage And Synthesis
Chemical Propertiesyellow powder
UsesTetrakis(triphenylphosphine)platinum(0), Pt is widely used in hydrosilation and oxidation. In Catalysts, Metal & Specialty Catalysts, Products & Industries.
reaction suitabilitycore: platinum
reagent type: catalyst
Purification MethodsIt forms yellow crystals on adding hexane to a cold saturated solution in *C6H6. It is soluble in *C6H6 and CHCl3 but insoluble in EtOH and hexane. A less pure product is obtained if it is crystallised by adding hexane to a CHCl3 solution. It is stable in air for several hours and completely stable under N2. [Malatesta & Cariello J Am Chem Soc 2323 1958, Beilstein 16 IV 955.]
Tetrakis(triphenylphosphine)platinum Preparation Products And Raw materials
Tag:Tetrakis(triphenylphosphine)platinum(14221-02-4) Related Product Information
Platinum Triphenylphosphine Bis(triphenylphosphine)palladium(II) chloride Tetrakis(triphenylphosphine)palladium Tetrabutyl titanate Platinum dioxide Palladium (II) Acetate Tetraphenylolethane glycidyl ether 4,4',4'',4'''-methanetetrayltetrabenzonitrile Tetrakis(4-aminophenyl)methane Tetrakis(dimethylsiloxy)silane Tetrakis(triphenylphosphine)nickel Bis(tri-tert-butylphosphine)palladium(0) Allylpalladium(II) Chloride Dimer Tris(triphenylphosphine)ruthenium(II) chloride Tetrakis(triphenylacetato)dirhodium(II) Tetrakis(trimethylsilyl)silane Tetrakis(dimethylamino)diboron