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ChemicalBook > Product Catalog >Organic Chemistry >Organometallic compounds >Organic palladium >Bis(tri-tert-butylphosphine)palladium(0)

Bis(tri-tert-butylphosphine)palladium(0)

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Company Name: Shaanxi Didu New Materials Co. Ltd
Tel: +86-89586680 +86-13289823923
Email: 1026@dideu.com
Products Intro: Product Name:Bis(tri-t-butylphosphine)palladium(0)
CAS:53199-31-8
Purity:99.0% Min Package:1g;1.5USD
Company Name: ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD
Tel: +86-13017695106 +86-13676922317
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Products Intro: Product Name:Bis(tri-t-butylphosphine)palladium
CAS:53199-31-8
Purity:99% Package:100KG;2USD|25KG;4USD|1KG;5USD
Company Name: Springchem New Material Technology Co.,Limited
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Products Intro: Product Name:Bis(tri-tert-butylphosphine)palladium(0)
CAS:53199-31-8
Purity:99%,99.5% Package:1kg,10kg,25kg
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
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Email: info@dakenam.com
Products Intro: Product Name:Bis(tri-tert-butylphosphine)palladium
CAS:53199-31-8
Purity:99% Package:1KG,5KG,10KG
Company Name: Henan Tianfu Chemical Co.,Ltd.
Tel: +86-0371-55170693 +86-19937530512
Email: info@tianfuchem.com
Products Intro: Product Name:Bis(tri-tert-butylphosphine)palladium(0)
CAS:53199-31-8
Purity:99% Package:25KG;5KG;1KG

Bis(tri-tert-butylphosphine)palladium(0) manufacturers
Bis(tri-tert-butylphosphine)palladium(0) Basic information
Reaction
Product Name:Bis(tri-tert-butylphosphine)palladium(0)
Synonyms:BIS(TRI-T-BUTYLPHOSPHINE)PALLADIUM(0);BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM;BIS(TRI-TERT-BUTYLPHOSPHINE)PALLADIUM (0);Bis(tri-t-butylphosphine)palladium(0),98%;Bis(tri-t-butyl)phosphino Pd0;Bis(tri-t-butylphosphine)palladium,;Bis(tri-tert-butylphosphin)palladium(0);Bis(tri-tert-butylphosphine)palladium (0) Reasonably stable for packaging and transfer.
CAS:53199-31-8
MF:C24H56P2Pd
MW:513.08
EINECS:640-284-9
Product Categories:chemical reaction,pharm,electronic,materials;organometallic phosphine complex;Catalysis and Inorganic Chemistry;Homogeneous Pd Catalysts;Palladium;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Pd
Mol File:53199-31-8.mol
Bis(tri-tert-butylphosphine)palladium(0) Structure
Bis(tri-tert-butylphosphine)palladium(0) Chemical Properties
Melting point >300 °C
storage temp. -20°C
form Crystals
color Off-white to orange-brown
Water Solubility insoluble
Sensitive Light, Air & Moisture Sensitive
InChIInChI=1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9;/h2*1-9H3;/q;;-2/p+2
InChIKeyXULQKWNZCKOVSU-UHFFFAOYSA-P
SMILESP(C(C)(C)C)(C(C)(C)C)(C(C)(C)C)[Pd]P(C(C)(C)C)(C(C)(C)C)C(C)(C)C
CAS DataBase Reference53199-31-8(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 24/25
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
ALFA English
Bis(tri-tert-butylphosphine)palladium(0) Usage And Synthesis
Reaction
  1. Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.
  2. A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.
  3. Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.
  4. Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.
  5. Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
  6. Cross-coupling of silanolates and halides.
  7. Elimination/isomerization of enol triflates derived from β-ketoesters.
 Reactions of 53199-31-8
Chemical PropertiesOff white crystalline solid
UsesCatalyst for Suzuki coupling on a multisubstituted sp 3 -carbon (eq. 1) Catalyst for Stille coupling reaction of aryl chlorides 2 (eq. 2) Catalyst for Negishi coupling reaction 3 (eq. 3) Catalyst for Heck coupling to form tetrasubstituted olefins 4 (eq. 4) Catalyst for Buchwald-Hartwig amination of aryl halide 5 (eq. 5) Catalyst for carbonylation of aryl halides with carbamoylsilanes 6 (eq. 6) t -Bu 3 P) 2 catalyst.
UsesBis(tri-tert-butylphosphine)palladium(0) is used in Coupling reactions, Heck couplings. It acts as a palladium catalyst for reductive carbonylation.
General DescriptionThis product has been enhanced for catalytic efficiency.
reaction suitabilitycore: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Bis(tri-tert-butylphosphine)palladium(0) Preparation Products And Raw materials
Raw materialsEthanol-->Tetrahydrofuran-->Toluene-->Acetonitrile-->Magnesium-->Phosphorus trichloride-->Hydrazine hydrate-->Palladium chloride-->2-Chloro-2-methylpropane
Tag:Bis(tri-tert-butylphosphine)palladium(0)(53199-31-8) Related Product Information
Tri-tert-butylphosphine T-BUTYLPHOSPHINE Diphenylphosphine tert-Butyldimethylsilyl chloride tert-Butanol Palladium (II) Acetate Dibutyltin dilaurate Tributylphosphine Tetrakis(triphenylphosphine)platinum Tris(triphenylphosphine)ruthenium(II) chloride Chlorodiphenylphosphine Palladium Tetrakis(triphenylphosphine)palladium tert-Butylchlorodiphenylsilane Allylpalladium(II) Chloride Dimer TRANS-DICHLOROBIS(TRIETHYLPHOSPHINE)PALLADIUM(II) Bis(acetonitrile)dichloropalladium(II) dichlorobis(di-tert-butylphenylphosphine)palladium(II)
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