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| | tert-Butyldichlorophosphine Basic information |
| | tert-Butyldichlorophosphine Chemical Properties |
| Melting point | 44-49 °C(lit.) | | Boiling point | 142-150 °C | | density | 0.766 g/mL at 25 °C | | storage temp. | Inert atmosphere,2-8°C | | form | Low Melting Crystalline Mass | | color | White to light yellow | | Water Solubility | Reacts with water. Soluble in n-Pentane, n-Hexane, Ether, Toluene,THF. tert-Butyldichlorophosphine is infinitely soluble in hydrocarbon and ethereal solvents. | | Sensitive | Air Sensitive | | Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents | | InChI | InChI=1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3 | | InChIKey | NMJASRUOIRRDSX-UHFFFAOYSA-N | | SMILES | C(P(Cl)Cl)(C)(C)C | | CAS DataBase Reference | 25979-07-1(CAS DataBase Reference) | | NIST Chemistry Reference | Tert-butyldichlorophosphine(25979-07-1) |
| | tert-Butyldichlorophosphine Usage And Synthesis |
| Chemical Properties | white to light yellow crystal powde | | Uses | Reactant for the synthesis of alkali metal complexes. As intermediates. tert-Butyldichlorophosphine (TBDCP) is used primarily in the preparation of monoand bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations and other asymmetric reactions as well as transition metal coupling reactions. This reagent is also used in the preparation of other phosphines in catalytic polymerization reactions. | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling |
| | tert-Butyldichlorophosphine Preparation Products And Raw materials |
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