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| | MANGANESE(II) ACETYLACETONATE Basic information |
| | MANGANESE(II) ACETYLACETONATE Chemical Properties |
| Melting point | 248-250 °C (dec.)(lit.) | | Boiling point | 130.3°C | | bulk density | 550kg/m3 | | density | 1,6 g/cm3 | | storage temp. | Store below +30°C. | | solubility | 11.5g/l | | form | Powder | | color | tan | | Specific Gravity | 1.60 | | Water Solubility | Soluble in water | | Sensitive | Hygroscopic | | Hydrolytic Sensitivity | 7: reacts slowly with moisture/water | | BRN | 4157965 | | Exposure limits | OSHA: Ceiling 5 mg/m3
NIOSH: IDLH 500 mg/m3; TWA 1 mg/m3; STEL 3 mg/m3 | | Stability: | hygroscopic | | InChI | 1S/2C5H8O2.Mn/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-; | | InChIKey | ZQZQURFYFJBOCE-FDGPNNRMSA-L | | SMILES | CC(=O)\C=C(\C)O[Mn]O\C(C)=C/C(C)=O | | EPA Substance Registry System | Manganese, bis(2,4-pentanedionato-.kappa.O,.kappa.O')- (14024-58-9) |
| Hazard Codes | Xn | | Risk Statements | 20/21/22-36/37/38-40 | | Safety Statements | 26-36 | | WGK Germany | 3 | | RTECS | OO9350000 | | TSCA | TSCA listed | | HS Code | 2914 19 90 | | Storage Class | 13 - Non Combustible Solids | | Hazard Classifications | Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Carc. 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | MANGANESE(II) ACETYLACETONATE Usage And Synthesis |
| Chemical Properties | Beige solid | | Uses | - Effect of Precursors on the Electrochemical Properties of Mixed RuOx/MnOx Electrodes Prepared by Thermal Decomposition.: This study investigates the impact of different precursors, including manganese(II) acetylacetonate, on the electrochemical properties of mixed RuOx/MnOx electrodes. The findings highlight the importance of precursor selection in optimizing electrode performance for energy storage applications (Petrucci et al., 2022).
- Trinuclear coordination assemblies of low-spin dicyano manganese(II) (S = 1/2) and iron(II) (S = 0) phthalocyanines with manganese(II) acetylacetonate, tris(cyclopentadienyl)gadolinium(III) and neodymium(III).: This research explores the formation and properties of trinuclear coordination complexes involving manganese(II) acetylacetonate. These complexes exhibit unique magnetic properties that have potential applications in molecular magnetism and materials science (Romanenko et al., 2022).
- ZIF-8 Membrane Permselectivity Modification by Manganese(II) Acetylacetonate Vapor Treatment.: This paper demonstrates how manganese(II) acetylacetonate vapor treatment can enhance the permselectivity of ZIF-8 membranes. Such modifications improve membrane performance in gas separation processes, offering advancements in industrial applications (Hayashi et al., 2021).
- Tuning the size and composition of manganese oxide nanoparticles through varying temperature ramp and aging time.: The study focuses on the synthesis of manganese oxide nanoparticles using manganese(II) acetylacetonate as a precursor. It outlines methods to control nanoparticle size and composition, which are critical for applications in catalysis and biomedicine (Martinez de la Torre et al., 2020).
- Manganese Oxide Nanoparticle Synthesis by Thermal Decomposition of Manganese(II) Acetylacetonate.: This research details the synthesis of manganese oxide nanoparticles via the thermal decomposition of manganese(II) acetylacetonate. The resulting nanoparticles show promise for use in various catalytic and biomedical applications (Martinez de la Torre and Bennewitz, 2020).
| | General Description | Manganese(II) acetylacetonate (Mn(acac)2) is a transition metal acetylacetonate that is trimeric in hydrocarbon solvents. It is monomeric and tetrahedral in its vapor state. It shows Mn-O bond energy of 65 kcal mol-1. It can be used with potassium permanganate in preparation of manganese triad (Mn(acac)3). | | reaction suitability | core: manganese | | Safety Profile | Questionable
carcinogen with experimental neoplastigenic
and tumorigenic data. When heated to
decomposition it emits acrid smoke and
irritating fumes. See also iMANGANESE
COMPOUNDS. | | Purification Methods | Purify it by stirring 16g of reagent for a few minutes with 100mL absolute EtOH and filter by suction as rapidly as possible through coarse filter paper. Sufficient EtOH is added to the filtrate, to make up for the loss of EtOH and to redissolve any solid that separates. Water (15mL) is added to the filtrate, and the solution is evaporated with a stream of N2 until reduced to half its volume. Cool for a few minutes and filter off the yellow crystals, dry them under a stream of N2, then in a vacuum at room temperature for 6-8hours. These conditions are important for obtaining the dihydrate. A vacuum to several mm of Hg or much lower pressure for several days produces the anhydrous complex. The degree of hydration can be established by determining the loss in weight of 100g of sample after heating for 4hours at 100o and <20mmHg. The theoretical loss in weight for 2H2O is 12.5%. The material sublimes at 200o/2mm. It is soluble in heptane, MeOH, EtOH or *C6H6 at 30o. [Charles Inorg Synth VI 164 1960, Fernelius & Biswas Inorg Synth V 105 1957, Beilstein 3 II 3122.] |
| | MANGANESE(II) ACETYLACETONATE Preparation Products And Raw materials |
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