|
| Methyl vinyl sulfone Basic information |
| Methyl vinyl sulfone Chemical Properties |
Boiling point | 115-117 °C19 mm Hg(lit.) | density | 1.212 g/mL at 25 °C(lit.) | refractive index | n20/D 1.463(lit.) | Fp | >230 °F | storage temp. | 2-8°C | form | Liquid | Specific Gravity | 1.212 | color | Clear colorless to slightly yellow | BRN | 878198 | Stability: | Stable. Incompatible with strong oxidizing agents. Irritant. | InChI | InChI=1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3 | InChIKey | WUIJTQZXUURFQU-UHFFFAOYSA-N | SMILES | C=CS(C)(=O)=O | CAS DataBase Reference | 3680-02-2(CAS DataBase Reference) | NIST Chemistry Reference | Ethene, (methylsulfonyl)-(3680-02-2) | EPA Substance Registry System | Ethene, (methylsulfonyl)- (3680-02-2) |
Hazard Codes | T+,T,Xi | Risk Statements | 22-27-41 | Safety Statements | 26-28-36/37/39-45-28A | RIDADR | UN 2810 6.1/PG 1 | WGK Germany | 3 | RTECS | WR6825000 | HazardClass | 6.1 | PackingGroup | II | HS Code | 29309099 |
| Methyl vinyl sulfone Usage And Synthesis |
Chemical Properties | light yellow liquid | Uses | Methyl vinyl sulfone has been used:
- as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometry
- in preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabric
- in Heck vinylation of aryl halides
| General Description | Clear pale yellow liquid. | Air & Water Reactions | Water soluble. | Reactivity Profile | Methyl vinyl sulfone is incompatible with oxidizing agents . Can react exothermically with reducing agents to release hydrogen gas or hydrogen sulfide. In the presence of various catalysts (such as acids) or initiatiators, can undergo exothermic polymerization reactions. | Fire Hazard | Methyl vinyl sulfone is probably combustible. | Purification Methods | Pass the sulfone through a column of alumina, then de-gas, distil it in a vacuum line and store it at -190o until required. [Beilstein 1 III 1866.] |
| Methyl vinyl sulfone Preparation Products And Raw materials |
|