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Methyl vinyl sulfone

Methyl vinyl sulfone Suppliers list
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Methyl vinyl sulfone Basic information
Product Name:Methyl vinyl sulfone
Synonyms:VINYL METHYL SULFONE;(methylsulfonyl)-ethen;1-(Methylsulfonyl)ethylene;Sulfone, methyl vinyl;sulfone,methylvinyl;URI 718;METHYL VINYL SULFONE;METHYL VINYL SULPHONE
CAS:3680-02-2
MF:C3H6O2S
MW:106.14
EINECS:222-958-0
Product Categories:Organic Building Blocks;Sulfones;Sulfur Compounds
Mol File:3680-02-2.mol
Methyl vinyl sulfone Structure
Methyl vinyl sulfone Chemical Properties
Boiling point 115-117 °C19 mm Hg(lit.)
density 1.212 g/mL at 25 °C(lit.)
refractive index n20/D 1.463(lit.)
Fp >230 °F
storage temp. 2-8°C
form Liquid
Specific Gravity1.212
color Clear colorless to slightly yellow
BRN 878198
Stability:Stable. Incompatible with strong oxidizing agents. Irritant.
InChIInChI=1S/C3H6O2S/c1-3-6(2,4)5/h3H,1H2,2H3
InChIKeyWUIJTQZXUURFQU-UHFFFAOYSA-N
SMILESC=CS(C)(=O)=O
CAS DataBase Reference3680-02-2(CAS DataBase Reference)
NIST Chemistry ReferenceEthene, (methylsulfonyl)-(3680-02-2)
EPA Substance Registry SystemEthene, (methylsulfonyl)- (3680-02-2)
Safety Information
Hazard Codes T+,T,Xi
Risk Statements 22-27-41
Safety Statements 26-28-36/37/39-45-28A
RIDADR UN 2810 6.1/PG 1
WGK Germany 3
RTECS WR6825000
HazardClass 6.1
PackingGroup II
HS Code 29309099
Storage Class6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
Hazard ClassificationsAcute Tox. 2 Dermal
Acute Tox. 4 Oral
Eye Dam. 1
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
Methyl vinyl sulfone Usage And Synthesis
Chemical Propertieslight yellow liquid
UsesMethyl vinyl sulfone has been used:
  • as derivatization reagent in an improved method for detection of pseudouridine in nucleoside mixtures by capillary HPLC-mass spectrometry
  • in preparation of methylsulfonylethyl cellulose via Michael addition to cotton fabric
  • in Heck vinylation of aryl halides
General DescriptionClear pale yellow liquid.
Air & Water ReactionsWater soluble.
Reactivity ProfileMethyl vinyl sulfone is incompatible with oxidizing agents . Can react exothermically with reducing agents to release hydrogen gas or hydrogen sulfide. In the presence of various catalysts (such as acids) or initiatiators, can undergo exothermic polymerization reactions.
Fire HazardMethyl vinyl sulfone is probably combustible.
Purification MethodsPass the sulfone through a column of alumina, then de-gas, distil it in a vacuum line and store it at -190o until required. [Beilstein 1 III 1866.]
Tag:Methyl vinyl sulfone(3680-02-2) Related Product Information
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