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2-Acrylamide-2-methylpropanesulfonic acid

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CAS:15214-89-8
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CAS:15214-89-8
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CAS:15214-89-8
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CAS:15214-89-8
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2-Acrylamide-2-methylpropanesulfonic acid Basic information
Product Name:2-Acrylamide-2-methylpropanesulfonic acid
Synonyms:1-Propanesulfonicacid,2-methyl-2-[(1-oxo-2-propenyl)amino]-;2-acrylamido-2-methylpropanesulfonate;1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-;2-ACRYLAMIDE-2-METHYLPROPANESULFONIC ACID;LABOTEST-BB LT00012662;2-Acryloylamino-2-methyl-1-propanesulfonic acid;2-ACRYLOYLAMIDO-2-METHYLPROPANESULFONIC ACID MONOMER;2-Acrylamide-2-MethyylPropaneSodiumSulfonate
CAS:15214-89-8
MF:C7H13NO4S
MW:207.25
EINECS:239-268-0
Product Categories:Organic Chemicals;Industrial/Fine Chemicals;monomer;Acrylamide and Methacrylamide;Acrylic Monomers;Monomers;bc0001;15214-89-8
Mol File:15214-89-8.mol
2-Acrylamide-2-methylpropanesulfonic acid Structure
2-Acrylamide-2-methylpropanesulfonic acid Chemical Properties
Melting point 195 °C (dec.) (lit.)
density 1.45
bulk density640kg/m3
vapor pressure <0.0000004 hPa (25 °C)
refractive index 1.6370 (estimate)
Fp 160 °C
storage temp. Store below +30°C.
solubility >500g/l soluble
pka1.67±0.50(Predicted)
form solution
color White
Water Solubility 1500 g/L (20 ºC)
Sensitive Hygroscopic
BRN 1946464
Stability:Light Sensitive
InChI1S/C7H13NO4S/c1-4-6(9)8-7(2,3)5-13(10,11)12/h4H,1,5H2,2-3H3,(H,8,9)(H,10,11,12)
InChIKeyHNKOEEKIRDEWRG-UHFFFAOYSA-N
SMILESCC(C)(CS(O)(=O)=O)NC(=O)C=C
LogP-3.7 at 20℃ and pH1-7
Surface tension70.5mN/m at 1g/L and 20℃
Dissociation constant2.4 at 20℃
CAS DataBase Reference15214-89-8(CAS DataBase Reference)
EPA Substance Registry System1-Propanesulfonic acid, 2-methyl-2-[(1-oxo-2-propenyl)amino]- (15214-89-8)
Safety Information
Hazard Codes C,Xn
Risk Statements 34-21/22-41-37-20/22
Safety Statements 26-36/37/39-45-22
RIDADR UN 2585 8/PG 3
WGK Germany 1
RTECS TZ6658000
TSCA TSCA listed
HazardClass 8
PackingGroup III
HS Code 29241900
Storage Class13 - Non Combustible Solids
Hazard ClassificationsAcute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
STOT SE 3
ToxicityLD50 orally in Rabbit: 1000 - 2000 mg/kg
MSDS Information
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2-Acrylamide-2-methylpropanesulfonic acid Usage And Synthesis
Chemical Properties2-Acrylamide-2-methylpropanesulfonic acid is a white crystals. The melting point is 195°C (decomposition). Soluble in water, the solution is acidic. Soluble in dimethylformamide, partially soluble in methanol, ethanol, insoluble in acetone. Slightly sour.
Uses2-Acrylamide-2-methylpropanesulfonic acid has good complexion, adsorption, biological activity, surface activity, hydrolysis stability and thermal stability. It can be used in oil chemical, water treatment, synthetic fiber, printing and dyeing, plastics, water absorbing coatings, paper, bio-medical, magnetic materials and cosmetics industries.
Preparation2-Acrylamido-2-methylpropanesulfonic acid(AMPS) can be synthesized by one step and two steps. The one-step method is to react the raw materials acrylonitrile, isobutylene and oleum together. The two-step method is to sulfonate isobutylene in the presence of a reaction solvent to obtain a sulfonated intermediate, and then react with acrylonitrile in the presence of sulfuric acid. One-step method is more economical. Raw material consumption quota: isobutylene 300kg/t, acrylonitrile 290kg/t, oleum 560kg/t.
Application2-Acrylamide-2-methylpropanesulfonic acid is an important monomer. Its copolymers or homopolymers with different molecular weight can be widely used in textile, oil drilling, water treatment, papermaking, dying, coating, cosmetics, electronics, etc. because of its unique formular structure—containing sulfonic acid group and unsaturated radical, thus showing excellent properties in many aspects.
DefinitionChEBI: 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid is an organosulfonic acid.
Solubility in organicsDMF, methanol (@ 65C), water
2-Acrylamide-2-methylpropanesulfonic acid Preparation Products And Raw materials
Raw materialsSulfuric acid-->Acetic acid-->FUMING SULFURIC ACID-->Acrylonitrile-->Isobutylene-->PROPYLENE-->Sulfuric acid fuming 20%
Preparation Products2-Acrylamido-2-methyl-1-propanesulfonic acid sodium salt-->N-TERT-BUTYLACRYLAMIDE
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