TRIS(CYCLOPENTADIENYL)LANTHANUM manufacturers
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| | TRIS(CYCLOPENTADIENYL)LANTHANUM Basic information |
| | TRIS(CYCLOPENTADIENYL)LANTHANUM Chemical Properties |
| Melting point | 275 °C (dec.)(lit.) | | Fp | >230 °F | | form | crystal | | color | white to off-white | | Sensitive | Air & Moisture Sensitive | | InChI | 1S/3C5H5.La/c3*1-2-4-5-3-1;/h3*1-5H; | | InChIKey | FRXJDKXOOBAPRG-UHFFFAOYSA-N | | SMILES | [La].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2.[CH]3[CH][CH][CH][CH]3 |
| Hazard Codes | F | | Risk Statements | 11-14/15 | | Safety Statements | 43-7/8 | | RIDADR | UN 3395 4.3/PG 2 | | WGK Germany | 3 | | HazardClass | 4.1 | | PackingGroup | III | | Storage Class | 4.3 - Hazardous materials which set free flammable gases upon contact with water | | Hazard Classifications | Flam. Sol. 2
Water-react 2 |
| | TRIS(CYCLOPENTADIENYL)LANTHANUM Usage And Synthesis |
| Chemical Properties | white crystal(s); air and moisture sensitive [STR93] | | Uses | Used as reducing agent for alkenes, organohalogen compounds, and organoheteroatom oxides; catalyst for
hydrogenation and isomerization of alkenes. | | Preparation | Because Cp3La is sensitive to air and moisture, the preparative procedure and all subsequent operations on the compound must be carried out with Schlenk techniques under purified argon. The following procedure has proven efficacious: to a suspension of anhydrous Lanthanum(III) Chloride in THF was added 4-5 equiv of sodium cyclopentadienide in THF; the mixture was refluxed with stirring for 4 h; the solvent was removed under reduced pressure, and the dry residue was transferred to a sublimation apparatus; on heating at 250-260 °C/10-3-10-4 mmHg, Cp3La sublimed as a white crystalline solid. Alternatively, the residue can be recrystallized from THF to afford Cp3La(THF) as colorless crystals. | | General Description | Atomic number of base material: 57 Lanthanum | | reaction suitability | core: lanthanum
reagent type: catalyst |
| | TRIS(CYCLOPENTADIENYL)LANTHANUM Preparation Products And Raw materials |
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