S-(2-thiopyridyl)mercaptopropionohydrazide

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S-(2-thiopyridyl)mercaptopropionohydrazide Basic information
Product Name:S-(2-thiopyridyl)mercaptopropionohydrazide
Synonyms:S-(2-thiopyridyl)mercaptopropionohydrazide;3-(2-Pyridyldithio)propionylhydrazide(PDPH);Propanoic acid, 3-(2-pyridinyldithio)-, hydrazide;3-(pyridin-2-yldisulfanyl)propanehydrazide;3-(2-Pyridyldisulfanyl)propanehydrazide;3-(2-dithiopyridyl)propanoic acidacylhydrazine
CAS:115616-51-8
MF:C8H11N3OS2
MW:229.32
EINECS:
Product Categories:Nitric Oxide Reagents;Cross Linking Reagents;Fluorescent Labels & Indicators;MTS & Sulfhydryl Active Reagents
Mol File:115616-51-8.mol
S-(2-thiopyridyl)mercaptopropionohydrazide Structure
S-(2-thiopyridyl)mercaptopropionohydrazide Chemical Properties
Melting point 87-90°C
Boiling point 463.6±41.0 °C(Predicted)
density 1.35±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
pka12.81±0.35(Predicted)
color White
Stability:Light Sensitive
InChI1S/C8H11N3OS2/c9-11-7(12)4-6-13-14-8-3-1-2-5-10-8/h1-3,5H,4,6,9H2,(H,11,12)
InChIKeyNITXODYAMWZEJY-UHFFFAOYSA-N
SMILESNNC(CCSSC1=NC=CC=C1)=O
Safety Information
WGK Germany WGK 3
Storage Class11 - Combustible Solids
MSDS Information
S-(2-thiopyridyl)mercaptopropionohydrazide Usage And Synthesis
Chemical PropertiesWhite Solid
UsesA fluorescent sulfhydryl active reagent.
General DescriptionThe PDPH is a heterobifunctional crosslinker containing sulfhydryl-reactive pyridyldithiol and carbonyl-reactive hydrazide moieties. Pyridyldithiols react with free sulfhydryls (-SH) to form disulfide bonds. Hydrazide groups react with carbonyls (aldehydes and ketones) to form stable hydrazone bonds. Aldehyde groups can be created by periodate-oxidation of sialic acid and other sugar components of glycoprotein polysaccharides. Thus, PDPH is useful for conjugating glycoproteins and sulfhydryl-containing peptides or proteins. Likewise, PDPH is useful as a sulfhydryl-addition reagent for glycoproteins and other carbohydrates; after reaction of the hydrazide to an oxidized carbohydrate, the pyridyldithiol group can be cleaved by a reducing agent to expose a sulfhydryl group. Yet another application for PDPH is to react the primary amine of the hydrazide moiety to a carboxyl group using the crosslinker EDC.
reaction suitabilityreagent type: cross-linking reagent
S-(2-thiopyridyl)mercaptopropionohydrazide Preparation Products And Raw materials
Tag:S-(2-thiopyridyl)mercaptopropionohydrazide(115616-51-8) Related Product Information
4-(4-N-maleimidophenyl)butyric acid hydrazide E-Maleimidopropionic acid hydrazide 11-Maleimidoundecanoic Acid Hydrazide 6-Maleimidocaproic acid hydrazide, trifluoroacetic acid S-(2-thiopyridyl)mercaptopropionohydrazide Propanoic acid, 3-(2-pyridinyldithio)-, hydrazide, hydrochloride (1:1)