| Company Name: |
Alfa Aesar |
| Tel: |
400-6106006 |
| Email: |
saleschina@alfa-asia.com |
| Company Name: |
Energy Chemical |
| Tel: |
400-0056266 |
| Email: |
sales8178@energy-chemical.com |
|
| | Ethyl 2-nitropropionate Basic information |
| | Ethyl 2-nitropropionate Chemical Properties |
| Boiling point | 75-76 °C/9 mmHg (lit.) | | density | 1.13 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.421(lit.) | | Fp | 193 °F | | storage temp. | Store at room temperature | | form | liquid | | pka | 5.98±0.10(Predicted) | | Appearance | Colorless to light yellow Liquid | | Water Solubility | Not miscible in water. | | BRN | 774734 | | InChI | 1S/C5H9NO4/c1-3-10-5(7)4(2)6(8)9/h4H,3H2,1-2H3 | | InChIKey | ZXBGJDZWJJFFQY-UHFFFAOYSA-N | | SMILES | CCOC(=O)C(C)[N+]([O-])=O | | EPA Substance Registry System | Propanoic acid, 2-nitro-, ethyl ester (2531-80-8) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36/37/39 | | RIDADR | NA 1993 / PGIII | | WGK Germany | 3 | | TSCA | TSCA listed | | HazardClass | IRRITANT | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | Ethyl 2-nitropropionate Usage And Synthesis |
| Uses | Ethyl 2-nitropropionate is used in the preparation of (-)-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst, novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion, 2-ethoxycarbonyl-2-nitropentanal. It is used for enantioselective Michael reactions. | | Uses | Ethyl 2-nitropropionate was used in the preparation of:
- ()-trans-2,5-dimethylprolineethyl ester via enantioselective Michael reaction methyl vinyl ketone using modified dihydroquinine as catalyst
- novel nitrogen-15-labeled nitrone spin trap, 5-ethoxycarbonyl-5-methyl-1-pyrroline N-oxide ([15N]EMPO) for detecting superoxide anion
- 2-ethoxycarbonyl-2-nitropentanal
| | General Description | Ethyl 2-nitropropionate is a nitro ester. |
| | Ethyl 2-nitropropionate Preparation Products And Raw materials |
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