| Company Name: |
Energy Chemical |
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400-0056266 |
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sales8178@energy-chemical.com |
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| | Dichlorotitanium diisopropoxide Basic information |
| | Dichlorotitanium diisopropoxide Chemical Properties |
| | Dichlorotitanium diisopropoxide Usage And Synthesis |
| Uses | Dichlorotitanium diisopropoxide is a Lewis acid frequently used in the preparation of chiral titanium complexes; an efficient catalyst for Diels-Alder reactions, [2 + 2] cycloadditions, and carbonyl-ene reactions, including asymmetric versions of these processes; a reagent for titanium enolate formation; and a catalyst component for the stereoselective addition of cyanide and allyltin nucleophiles to aldehydes. | | Preparation | Dichlorotitanium diisopropoxide is prepared by adding slowly at rt an equimolar amount of Titanium(IV) Chloride to a hexane solution of Titanium Tetraisopropoxide; following mixing, during which heat is evolved, the mixture is allowed to stand at rt for 6 h and the precipitate is collected and washed with hexane; dibromotitanium diisopropoxide is prepared similarly. | | storage | Corrosive; moisture sensitive; use in a fume hood; can be stored under nitrogen in pure form or in solution. |
| | Dichlorotitanium diisopropoxide Preparation Products And Raw materials |
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