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(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC

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(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC Basic information
Reactions
Product Name:(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC
Synonyms:(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium (IV) dichloride;(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct;(4R,5R)-(-)-2,2-Dimethyl-a,a,a',a'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct;(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV)dichlorideacetonitrileadduct;(4R,5R)-(-)-2,2-Dimethyl-alpha,alpha,alpha',alpha'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato(1,2-bis(dimethoxy)ethane)titanium(IV) dichloride acetonitrile addu;'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct;(4R,5R)-(-)-2,2-Dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride;(4R,5R)-(-)-2,2-Dimethyl-α,α,α'',α''-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) dichloride acetonitrile adduct
CAS:328123-04-2
MF:C31H30Cl2O4Ti.C4H10O2.C2H3N
MW:716.521
EINECS:
Product Categories:Chiral Oxygen;TADDOL Series
Mol File:328123-04-2.mol
(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC Structure
(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC Chemical Properties
form crystal
color white
Sensitive air sensitive, moisture sensitive
Safety Information
MSDS Information
(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC Usage And Synthesis
Reactions
  1. Catalyst used in the enantioselective fluorination of β-ketoesters.
  2. Versatile catalyst used in the enantioselective 1,2 and 1,4 additions to carbonyl compounds, transfer of allyl groups to aldehydes, cycloadditions and others.  
Reactions of 328123-04-2
(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC Preparation Products And Raw materials
Tag:(4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC(328123-04-2) Related Product Information
1-[(3aR,8aR)-tetrahydro-2,2-diMethyl-4,4,8,8-tetraphenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl]- Piperidine 1-[(3aS,8aS)-tetrahydro-2,2-diMethyl-4,4,8,8-tetraphenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl]-Pyrrolidine 1-[(3aS,8aS)-tetrahydro-2,2-diMethyl-4,4,8,8-tetraphenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl]- Piperidine 1-[(3aR,8aR)-tetrahydro-2,2-diMethyl-4,4,8,8-tetraphenyl-1,3-dioxolo[4,5-e][1,3,2]dioxaphosphepin-6-yl]-Pyrrolidine Titanium dichloride diethoxide Dichlorotitanium diisopropoxide (4R,5R)-(-)-2,2-Dimethyl-tetraphenyl-1,3-dioxolane-4,5-dimethanolato[1,2-bis(dimethoxy)ethane]titanium(IV) DIC 4-Methyl-1-phenyl-hex-5-en-3-ol Phenylethyl acetal butoxytitanium dichloride [2-(1-butoxyethoxy)ethyl]benzene