2,2' - [硫代羰酰 (硫)]双[2 -甲基丙酸]
| 中文名称 | 2,2' - [硫代羰酰 (硫)]双[2 -甲基丙酸] |
|---|---|
| 中文同义词 | 2,2'-[硫代羰酰双(硫)]双[2-甲基丙酸];2,2' - [硫代羰酰 (硫)]双[2 -甲基丙酸];2,2'-[甲硫代基双(硫代)]双[2-甲基丙酸;2,2'-(硫代羰基双(硫烷二基))双(2-甲基丙酸);2,2'-[甲硫代基双(硫代)]双[2-甲基丙酸]?,97%;2,2' - [硫代羰酰 (硫)]双[2 -甲基丙酸;2,2'-[甲硫代基双(硫代)]双[2-甲基丙酸];2,2'-[硫代羰酰双(硫)]双[2-甲基丙酸 |
| 英文名称 | 2,2'-[(Thioxomethylene)disulfanyl]bis(2-methylpropanoic acid) |
| 英文同义词 | 2,2'-[Carbonothioylbis(thio)]bis[2-methylpropanoicacid],min.97%;2,2'-[Carbonothioylbis(thio)]bis[2-methylpropanoic acid];Propanoic acid, 2,2'-[carbonothioylbis(thio)]bis[2-methyl-;S,S'-bis(α,α'-dimethyl-α"-acetic acid)-trithiocarbonate;2,2'-(Carbonothioyldisulfanediyl)bis(2-methylpropanoic acid);S,S'-Bis(a,a'-dimethyl-a''-acetic acid)trithiocarbonate;2,2'-(Thiocarbonylbis(sulfanediyl))bis(2-methylpropanoic acid);2,2'-[Carbonothioylbis(thio)]bis[2-methylpropanoic acid],97% |
| CAS号 | 355120-40-0 |
| 分子式 | C9H14O4S3 |
| 分子量 | 282.4 |
| EINECS号 | |
| 相关类别 | |
| Mol文件 | 355120-40-0.mol |
| 结构式 | ![2,2' - [硫代羰酰 (硫)]双[2 -甲基丙酸] 结构式](CAS/GIF/355120-40-0.gif) |
2,2' - [硫代羰酰 (硫)]双[2 -甲基丙酸] 性质
| 熔点 | 178℃ |
|---|---|
| 沸点 | 495.437±38.00 °C(Press: 760.00 Torr)(predicted) |
| 密度 | 1.416±0.06 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted) |
| 酸度系数(pKa) | 2.532±0.10(predicted) |
| 形态 | 晶体 |
| 颜色 | 橙色 |
| InChI | InChI=1S/C9H14O4S3/c1-8(2,5(10)11)15-7(14)16-9(3,4)6(12)13/h1-4H3,(H,10,11)(H,12,13) |
| InChIKey | KFNUBPMMXWWWGU-UHFFFAOYSA-N |
| SMILES | C(SC(C)(C)C(O)=O)(SC(C)(C)C(O)=O)=S |
可作为RAFT试剂使用
[2] Repeatable Photoinduced Self-Healing of Covalently Cross-Linked Polymers through Reshuffling of Trithiocarbonate Units. https://doi.org/10.1002/anie.201003888
[3] Direct Synthesis of Thermally Responsive DMA/NIPAM Diblock and DMA/NIPAM/DMA Triblock Copolymers via Aqueous, Room Temperature RAFT Polymerization. https://doi.org/10.1021/ma0523419
参考文献
[1] Functional Polymers from Novel Carboxyl-Terminated Trithiocarbonates as Highly Efficient RAFT Agents. https://doi.org/10.1021/ma020362m
[2] Repeatable Photoinduced Self-Healing of Covalently Cross-Linked Polymers through Reshuffling of Trithiocarbonate Units. https://doi.org/10.1002/anie.201003888
[3] Direct Synthesis of Thermally Responsive DMA/NIPAM Diblock and DMA/NIPAM/DMA Triblock Copolymers via Aqueous, Room Temperature RAFT Polymerization. https://doi.org/10.1021/ma0523419
安全信息
| 海关编码 | 2930909899 |
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