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Alfa Aesar |
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400-6106006 |
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- 4-AMINOBENZOPHENONE
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- $1.00
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2019-12-20
- CAS:1137-41-3
- Min. Order: 1ASSAYS
- Purity: 97-99%
- Supply Ability: 1000KGS
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| | 4-Aminobenzophenone Basic information |
| | 4-Aminobenzophenone Chemical Properties |
| Melting point | 121-124 °C (lit.) | | Boiling point | 246 °C (12.7517 mmHg) | | density | 1.0957 (rough estimate) | | refractive index | 1.6050 (estimate) | | Fp | 245-247°C/22mm | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | form | Fine Crystalline Powder | | pka | pK1: 2.15(+1) (25°C) | | color | Yellow | | Water Solubility | Soluble in cold water, alcohol and ether. | | BRN | 389292 | | InChI | InChI=1S/C13H11NO/c14-12-8-6-11(7-9-12)13(15)10-4-2-1-3-5-10/h1-9H,14H2 | | InChIKey | RBKHNGHPZZZJCI-UHFFFAOYSA-N | | SMILES | C(C1=CC=C(N)C=C1)(C1=CC=CC=C1)=O | | CAS DataBase Reference | 1137-41-3(CAS DataBase Reference) | | EPA Substance Registry System | Methanone, (4-aminophenyl)phenyl- (1137-41-3) |
| Hazard Codes | Xi | | Risk Statements | 36/37/38-22 | | Safety Statements | 26-36-37/39 | | WGK Germany | 3 | | RTECS | DJ0175000 | | F | 8-10-23 | | TSCA | TSCA listed | | HazardClass | IRRITANT | | HS Code | 29223990 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Acute Tox. 4 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | 4-Aminobenzophenone Usage And Synthesis |
| Chemical Properties | YELLOW FINE CRYSTALLINE POWDER | | Uses | 4-Aminobenzophenone is associated with 4-benzoylpyridine and it is used as a frequency doubler for semiconductor lasers. It is used in the preparation of 1-[4-[N,N-bis(trimethylsilyl)amino]phenyl]-1-phenylethylene. It is used as a precursor to prepare 1,2,3-triazoles, pyrimidotriazoles, benzothiazole and pyrimidinone derivatives. It is involved in the formation of coordination complexes with chromium(III). | | Synthesis Reference(s) | Tetrahedron Letters, 39, p. 1313, 1998 DOI: 10.1016/S0040-4039(97)10877-2 | | General Description | 4-Aminobenzophenone (4-ABP) is the best derivative of benzophenone with 260 times higher second harmonic generation (SHG) efficiency than potassium dihydrogen phosphate (KDP), growth of high quality bulk crystal still remains a difficult task. | | Safety Profile | Poison by intraperitoneal route. See also KETONES and AMINES. When heated to decomposition it emits toxic fumes of NOx,. | | Purification Methods | Dissolve it in aqueous acetic acid, filter and precipitate it with ammonia. This process is repeated several times, then the amine is recrystallised from aqueous EtOH. [Beilstein 14 IV 248.] |
| | 4-Aminobenzophenone Preparation Products And Raw materials |
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