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Bis(4-trifluoromethylphenyl)phosphine

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Bis(4-trifluoromethylphenyl)phosphine Basic information
Product Name:Bis(4-trifluoromethylphenyl)phosphine
Synonyms:potassium bis(4-(trifluoromethyl)phenyl)phosphide;DI-(4-TRIFLUOROMETHYLPHENYL)PHOSPHINE;Bis(4-trifluoromethylphenyl)phosphine,98%;Bis(4-trifluoromethylphenyl)phosphine 97%;Phosphine, bis[4-(trifluoromethyl)phenyl]-;Bis(4-trifluoromethylphenyl)phosphine
CAS:99665-68-6
MF:C14H9F6P
MW:322.19
EINECS:
Product Categories:
Mol File:99665-68-6.mol
Bis(4-trifluoromethylphenyl)phosphine Structure
Bis(4-trifluoromethylphenyl)phosphine Chemical Properties
Boiling point 291.4±40.0 °C(Predicted)
density 1.317 g/mL at 25 °C
refractive index n20/D1.512
form liquid
InChI1S/C14H9F6P/c15-13(16,17)9-1-5-11(6-2-9)21-12-7-3-10(4-8-12)14(18,19)20/h1-8,21H
InChIKeyLLJITAAISCMRAR-UHFFFAOYSA-N
SMILESFC(F)(F)c1ccc(Pc2ccc(cc2)C(F)(F)F)cc1
Safety Information
Hazard Codes T
Risk Statements 25-37-41
Safety Statements 26-39-45
RIDADR UN 2810 6.1 / PGIII
WGK Germany WGK 3
Storage Class6.1D - Non-combustible acute toxic Cat.3
toxic hazardous materials or hazardous materials causing chronic effects
Hazard ClassificationsAcute Tox. 3 Oral
Aquatic Chronic 4
Eye Dam. 1
MSDS Information
Bis(4-trifluoromethylphenyl)phosphine Usage And Synthesis
UsesReactant for:
  • Preparation of iron(II) chiral diimine diphosphine complexes as catalysts for asymmetric transfer hydrogenation of ketones
  • Enantioselective decarboxylative allylation and ring-closing metathesis
reaction suitabilityreagent type: ligand
Bis(4-trifluoromethylphenyl)phosphine Preparation Products And Raw materials
Tag:Bis(4-trifluoromethylphenyl)phosphine(99665-68-6) Related Product Information
2-[Bis(4-trifluoromethylphenyl)phosphino]ethylamine (4-Trifluoromethylphenyl)phosphine Tris(4-trifluoromethylphenyl)phosphine (R)-1-[(S)-2-[Bis[4-(trifluoromethyl)phenyl]phosphino]ferrocenyl]-ethyldi-tert-butylphosphine (+)-O-Isopropylidene-2,3-dihydroxy-1,4-bis[bis(4-trifluoromethylphenyl)phosphino]butane Bis(4-trifluoromethylphenyl)chlorophosphine Chlorotris(para-trifluoromethylphenyl)phosphine gold(I) (S)-(-)-[(S)-2-Di(3,5-xylyl)phosphinoferrocenyl][2-di(4-trifluoromethylphenyl)phosphinophenyl]methanol Bis(4-trifluoromethylphenyl)phosphine Bis(2,2-dimethylpropanoato)(4-methylphenyl)bis[tris[4-(trifluoromethyl)phenyl]phosphine]rhodium