PCN-222(FE)金属有机骨架
| 中文名称 | PCN-222(FE)金属有机骨架 |
|---|---|
| 中文同义词 | PCN-222(FE)金属有机骨架;PCN-222模拟过氧化物酶 |
| 英文名称 | PCN-222 |
| 英文同义词 | PCN-222;PCN-222 mimetic peroxidase;PCN-222(Fe) |
| CAS号 | 1403461-00-6 |
| 分子式 | C96H48Cl2Fe2N8O32Zr6 |
| 分子量 | 2555.4 |
| EINECS号 | |
| 相关类别 | MOF |
| Mol文件 | 1403461-00-6.mol |
| 结构式 | ![]() |
PCN-222(FE)金属有机骨架 性质
| 配位金属 | Zr |
| 配体 | 4-羧基苯基卟啉铁(CAS:55266-17-6) |
| 孔径 | 3.7nm;1.3nm |
| 孔容 | 1.5cm3/g |
| 粒径 | 2um*10um棒状晶粒 |
| 比表面 | BET比表面>2000m2/g |
PCN-222(Fe)在空气中稳定,在水溶液和酸性条件下稳定;高热稳定性、热分解温度约400℃。
PCN-222具有稳定的一维孔道,可负载金属催化剂或储气及吸附材料参考文献
[1] Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts. https://doi.org/10.1002/ange.201204475
[2] Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks. https://doi.org/10.1021/ic300825s
[3] From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media. https://doi.org/10.1002/anie.201803262
[4] Single-Atom Electrocatalysts from Multivariate Metal–Organic Frameworks for Highly Selective Reduction of CO₂ at Low Pressures. https://doi.org/10.1002/anie.202008787
[5] Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction. https://doi.org/10.1039/c9ta10206j
