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Tetrakis(acetonitrile)palladium(II) tetrafluoroborate manufacturers
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| | Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Basic information |
| Product Name: | Tetrakis(acetonitrile)palladium(II) tetrafluoroborate | | Synonyms: | Tetrakis(acetonitrile)palladium(II)tetrafluoroborate,99%;PALLADIUM(II) TETRAFLUOROBORATE-TETRAACETONITRILE COMPLEX;TETRAKIS(ACETONITRILE)PALLADIUM(II) TETRAFLUOROBORATE (30%PD);Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, Pd 23.9%;Tetrakis(acetonitrile)palladiuM(II) tetrafluoroborate, 99% 1GR;NSC 307191;Tetrakis(acetonitrile)palladium(II) tetrafluoroborate, min. 98%;Acetonitrile,palladium(2+),ditetrafluoroborate | | CAS: | 21797-13-7 | | MF: | C8H12BF4N4Pd+ | | MW: | 357.44 | | EINECS: | | | Product Categories: | Pd;organometallic complex | | Mol File: | 21797-13-7.mol |  |
| | Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Chemical Properties |
| Melting point | 230 °C (dec.) (lit.) | | storage temp. | Inert atmosphere,2-8°C | | form | Powder | | color | Yellow | | Water Solubility | Soluble in water | | Sensitive | Air Sensitive | | InChI | 1S/4C2H3N.2BF4.Pd/c4*1-2-3;2*2-1(3,4)5;/h4*1H3;;;/q;;;;2*-1;+2 | | InChIKey | YWMRPVUMBTVUEX-UHFFFAOYSA-N | | SMILES | [Pd++].CC#N.CC#N.CC#N.CC#N.F[B-](F)(F)F.F[B-](F)(F)F |
| Hazard Codes | Xn | | Risk Statements | 20 | | Safety Statements | 22-36/37/39-38 | | RIDADR | UN2811 | | WGK Germany | 3 | | HazardClass | 6.1 | | PackingGroup | III | | HS Code | 29310099 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Acute Tox. 4 Inhalation |
| | Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Usage And Synthesis |
| Chemical Properties | Yellow powder | | Uses | Tetrakis(acetonitrile)palladium Bis(tetrafluoroborate) is used to prepare an α-Diimine-transition metal complex, which is used as a catalyst for polymerization of olefins. It is also a catalyst used in cross coupling reaction for C-C, C-O, and C-N bond formation. | | Uses | Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Reactant involved in:
- Reactions where it plays a role as the metal source due to weakly coordinated acetonitrile ligands
Precursor for:
- Synthesis of dendritic SCS-pincer palladium complexes
- Palladium complexes of click ligands
- Dipalladium catalysts for use in Heck cross-coupling, Suzuki cross-coupling, and aldehyde olefination
| | General Description | Tetrakis(acetonitrile)palladium(II) tetrafluoroborate is a stronger Lewis acid. It participates in the preparation of 2:1 complex [Pd(1,2-bis(2′-pyridylethynyl)benzene)2](BF4]2, by Sonogashira cross-coupling reaction. | | reaction suitability | reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
core: palladium
reagent type: ligand |
| | Tetrakis(acetonitrile)palladium(II) tetrafluoroborate Preparation Products And Raw materials |
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