Tetrakis(acetonitrile)copper(I) tetrafluoroborate manufacturers
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| | Tetrakis(acetonitrile)copper(I) tetrafluoroborate Basic information |
| | Tetrakis(acetonitrile)copper(I) tetrafluoroborate Chemical Properties |
| Melting point | 164 °C(dec.) | | density | 1.466 g cm-3 | | storage temp. | Inert atmosphere,Room Temperature | | solubility | soluble in toluene, CH2Cl2, MeCN. | | form | powder to crystal | | color | White to Almost white | | Decomposition | 270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition) | | InChI | InChI=1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1 | | InChIKey | YZGSKMIIVMCEFE-UHFFFAOYSA-N | | SMILES | [B+3]([F-])([F-])([F-])[F-].[Cu+](N#CC)(N#CC)(N#CC)N#CC |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45 | | RIDADR | UN 1759 8/PG 2 | | WGK Germany | 3 | | HazardClass | 8 | | PackingGroup | III | | HS Code | 29269090 | | Storage Class | 8A - Combustible corrosive hazardous materials | | Hazard Classifications | Skin Corr. 1B |
| | Tetrakis(acetonitrile)copper(I) tetrafluoroborate Usage And Synthesis |
| Chemical Properties | White crystalline powder | | Uses | Catalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction. | | General Description | This product has been enhanced for catalytic efficiency. | | reaction suitability | core: copper
reagent type: catalyst | | Synthesis | The Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
| | Precautions | Irritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.
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| | Tetrakis(acetonitrile)copper(I) tetrafluoroborate Preparation Products And Raw materials |
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