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Tetrakis(acetonitrile)copper(I) tetrafluoroborate

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Company Name: TCI (Shanghai) Development Co., Ltd.  Gold
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Company Name: Shanghai Bihe Biochemical Technology Co., Ltd  Gold
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Tetrakis(acetonitrile)copper(I) tetrafluoroborate Basic information
Product Name:Tetrakis(acetonitrile)copper(I) tetrafluoroborate
Synonyms:Tetrakis(acetonitrile)copper(I) tetrafluoroborate;Copper(1+) tetrafluoroborate acetonitrile (1:1:4);e)copper(I) TetrafL;Tetrakis(acetonitriL;Tetrakis(acetonitrile)copper(I) tetrafluoroborate 97%;Tetra(acetonitrile)copper(1+) tetrafluoroborate;Tetra(acetonitrile)copper(1+) tetraflu;Copper(1+), tetrakis(acetonitrile)-, (T-4)-, tetrafluoroborate(1-)
CAS:15418-29-8
MF:C8H12BCuF4N4
MW:314.56
EINECS:
Product Categories:Catalysis and Inorganic Chemistry;Chemical Synthesis;Copper
Mol File:15418-29-8.mol
Tetrakis(acetonitrile)copper(I)  tetrafluoroborate Structure
Tetrakis(acetonitrile)copper(I) tetrafluoroborate Chemical Properties
Melting point 164 °C(dec.)
density 1.466 g cm-3
storage temp. Inert atmosphere,Room Temperature
solubility soluble in toluene, CH2Cl2, MeCN.
form powder to crystal
color White to Almost white
Decomposition 270 °C (161-171 °C, sealed tube; 167-169 °C with decomposition)
InChIInChI=1S/4C2H3N.BF4.Cu/c4*1-2-3;2-1(3,4)5;/h4*1H3;;/q;;;;-1;+1
InChIKeyYZGSKMIIVMCEFE-UHFFFAOYSA-N
SMILES[B+3]([F-])([F-])([F-])[F-].[Cu+](N#CC)(N#CC)(N#CC)N#CC
Safety Information
Hazard Codes C
Risk Statements 34
Safety Statements 26-36/37/39-45
RIDADR UN 1759 8/PG 2
WGK Germany 3
HazardClass 8
PackingGroup III
HS Code 29269090
Storage Class8A - Combustible corrosive hazardous materials
Hazard ClassificationsSkin Corr. 1B
MSDS Information
Tetrakis(acetonitrile)copper(I) tetrafluoroborate Usage And Synthesis
Chemical PropertiesWhite crystalline powder
UsesCatalyst in Diels-Alder and Ullmann reactions, intramolecular aromatic annulations, ring expansions in steroids, asymmetric aziridination of alkenes, substitution of allylic halides and mesylates, the Kharasch-Sosnovsky reaction.
General DescriptionThis product has been enhanced for catalytic efficiency.
reaction suitabilitycore: copper
reagent type: catalyst
SynthesisThe Preparative Method of Tetrakis(acetonitrile)copper(I) Tetrafluoroborate: Several available, e.g. modification of the known hexafluorophosphate procedure, addition of Acetonitrile to the CuBF4-toluene complex, and treatment of Copper(I) Oxide with Boron Trifluoride Etherate in MeCN.
PrecautionsIrritant; moisture sensitive; handle under inert atmosphere. Use in a fume hood.
Tetrakis(acetonitrile)copper(I) tetrafluoroborate Preparation Products And Raw materials
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