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| | Cyclooctene oxide Basic information |
| | Cyclooctene oxide Chemical Properties |
| Melting point | 53-56 °C(lit.) | | Boiling point | 55 °C5 mm Hg(lit.) | | density | 0.9090 (rough estimate) | | refractive index | 1.4540 (estimate) | | Fp | 133 °F | | storage temp. | 2-8°C | | solubility | soluble in Methanol | | form | powder to crystal | | color | White to Almost white | | BRN | 103543 | | InChI | 1S/C8H14O/c1-2-4-6-8-7(9-8)5-3-1/h7-8H,1-6H2 | | InChIKey | MELPJGOMEMRMPL-UHFFFAOYSA-N | | SMILES | C1CCCC2OC2CC1 | | CAS DataBase Reference | 286-62-4(CAS DataBase Reference) |
| Hazard Codes | Xn,F | | Risk Statements | 22-36/38-11 | | Safety Statements | 26-37/39 | | RIDADR | UN 1325 4.1/PG 3 | | WGK Germany | 2 | | F | 10-21 | | HazardClass | 4.1 | | PackingGroup | III | | HS Code | 29109000 | | Storage Class | 4.1B - Flammable solid hazardous materials | | Hazard Classifications | Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Sol. 1
Skin Irrit. 2 |
| | Cyclooctene oxide Usage And Synthesis |
| Chemical Properties | COLOURLESS TO WHITE ADHERING CRYSTALS OR CHUNKS | | Synthesis Reference(s) | The Journal of Organic Chemistry, 43, p. 1689, 1978 DOI: 10.1021/jo00403a015
Tetrahedron Letters, 27, p. 2617, 1986 DOI: 10.1016/S0040-4039(00)84599-2 | | Purification Methods | It can be distilled in vacuum, and the solidified distillate can be sublimed in vacuum below 50o. It has a characteristic odour. [IR: Cope et al. J Am Chem Soc 74 5884 1952, cf trans-isomer: Cope et al. J Am Chem Soc 79 3905 1957, Reppe et al. Justus Liebigs Ann Chem 560 1 1948]. |
| | Cyclooctene oxide Preparation Products And Raw materials |
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