N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 基本信息
| 中文名称 | N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 |
|---|---|
| 中文同义词 | N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺;9H-芴-2-胺,N-[1,1'-联苯]-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基;N-(苯基-4-基)-9,9-二甲基-N-(4-(9-苯基-9H-咔唑-3-基)苯基)-9H-芴-2-胺;N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺N-(苯基-4-基)-9,9-二甲基-N-(4-(9-苯基-9H-咔唑-3-基)苯基)-9H-芴-2-胺;N-(4-联苯基)-N-(9,9-二甲基芴-2-基)-N-(4-(3-N-苯基咔唑)苯基)胺;N-[3-[1,1′-联苯]基]-9,9-二甲基-N-[4-[9-苯基-9H-咔唑-3-基]苯基]-9H-芴-2-胺;N-(4-联苯)-9,9-二甲基-N-(4-(9-苯基-9H-咔唑-3-基)-9H-芴-2-胺;N-[1,1′-联苯]-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 |
| 英文名称 | 9H-Fluoren-2-aMine, N-[1,1'-biphenyl]-4-yl-9,9-diMethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]- |
| 英文同义词 | 9H-Fluoren-2-aMine, N-[1,1'-biphenyl]-4-yl-9,9-diMethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-;N-[1,1'-Diphenyl]-4-yl-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine;N-(biphenyl-4-yl)-9,9-dimethyl-N-(4-(9-phenyl-9H-carbazol-3-yl)phenyl)-9H-fiuoren-2-amine;9H-Fluoren-2-Amine,N-[1,1'-biphenyl]-4-yl-9,9-diMethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl, 99.5%;Biphenyl-4-yl-(9,9-dimethyl-9H-fluoren-2-yl)-[4-(9-phenyl-8a,9-dihydro-4bH-carbazol-3-yl)-phenyl]-amine;N-(4-Biphenylyl)-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine;N-[[1,1′-biphenyl]-3-yl]-9,9-dimethyl-N-[4-[9-phenyl-9H-carbazol-3-yl]phenyl]-9H-fluoren-2-amine;N-[1,1'-Diphenyl]-4-yl-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluorene-2-amine |
| CAS号 | 1242056-42-3 |
| 分子式 | C51H38N2 |
| 分子量 | 678.86 |
| EINECS号 | |
| 相关类别 | 中间体-有机合成中间体;共轭芳烃;咔唑;医药中间体;OLED终端体材料;杂环类;OLED光电材料 |
| Mol文件 | 1242056-42-3.mol |
| 结构式 | ![N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 结构式](CAS/GIF/1242056-42-3.gif) |
N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 性质
| 密度 | 1.14 |
|---|---|
| 储存条件 | Keep in dark place,Sealed in dry,Room Temperature |
| 形态 | powder |
| 酸度系数(pKa) | -2.80±0.40(Predicted) |
| 颜色 | white to yellow |
| InChIKey | GJWBRYKOJMOBHH-UHFFFAOYSA-N |
| SMILES | [n]2(c3c(c%10c2cccc%10)cc(cc3)c4ccc(cc4)N(c8ccc(cc8)c9ccccc9)c5cc6c(cc5)c7c(cccc7)C6(C)C)c1ccccc1 |
![N-[1,1'-联苯-4-基]-9,9-二甲基-9H-芴-2-胺](/CAS/GIF/897671-69-1.gif)
897671-69-1
1028647-93-9
![N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺](/CAS/GIF/1242056-42-3.gif)
1242056-42-3
以N-([1,1'-联苯]-4-基)-9,9-二甲基-9H-芴-2-胺和3-(4-溴苯基)-9-苯基咔唑为原料合成N-联苯-4-基-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺的一般步骤：将3-(4-溴苯基)-9-苯基-9H-咔唑（9.6 g，24 mmol）溶解于甲苯中，加入N-([1,1'-联苯]-4-基)-9,9-二甲基-9H-芴-2-胺（7.2 g，20 mmol）、三(二亚苄基丙酮)二钯（Pd2(dba)3，0.05当量）、三苯基膦（PPh3，0.1当量）和叔丁醇钠（NaOt-Bu，3当量）。将反应混合物加热至100℃，回流搅拌24小时。反应完成后，对所得有机物进行萃取，有机层用无水硫酸镁（MgSO4）干燥，通过硅胶柱层析纯化（洗脱剂：乙醚/水），最后通过重结晶得到目标化合物13.8 g（产率：85%）。
参考文献：
[1] Patent: KR101493482, 2015, B1. Location in patent: Paragraph 0126; 0202-0204
[2] Patent: KR2015/31892, 2015, A. Location in patent: Paragraph 0235-0237
[3] Patent: KR101614738, 2016, B1. Location in patent: Paragraph 0401-0403
[4] Patent: KR101857632, 2018, B1. Location in patent: Paragraph 0334; 0341-0343
[5] Patent: US2017/288147, 2017, A1. Location in patent: Paragraph 0132; 0133
安全信息
| WGK Germany | WGK 3 |
|---|---|
| 存储类别 | 11 - 可燃固体 |
| 更新日期 | 产品编号 | 产品名称 | CAS号 | 包装 | 价格 |
|---|---|---|---|---|---|
| 2025/12/22 | B5435 | N-([1,1'-联苯]-4-基)-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 N-[[1,1'-Biphenyl]-4-yl]-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine | 1242056-42-3 | 1G | 630元 |
| 2025/12/22 | B5435 | N-([1,1'-联苯]-4-基)-9,9-二甲基-N-[4-(9-苯基-9H-咔唑-3-基)苯基]-9H-芴-2-胺 N-[[1,1'-Biphenyl]-4-yl]-9,9-dimethyl-N-[4-(9-phenyl-9H-carbazol-3-yl)phenyl]-9H-fluoren-2-amine | 1242056-42-3 | 5G | 1625元 |