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| | (2-NAPHTHYL)METHYLZINC BROMIDE Basic information |
| Product Name: | (2-NAPHTHYL)METHYLZINC BROMIDE | | Synonyms: | (2-NAPHTHYL)METHYLZINC BROMIDE;(2-NAPHTHYLMETHYL)ZINC BROMIDE, 0.5M SOL UTION IN TETRAHYDROFURAN;(2-naphthylmethyl)zinc bromide solution;(2-Naphthylmethyl)zinc bromide solution 0.5M in THF;(2-Naphthyl)methylzinc bromide 0.5 M in Tetrahydrofuran;(2-Naphthylmethyl)zinc bromide solution 0.5 in THF;(2-Naphthylmethyl)zinc bromide, 0.50 M in THF - [N73099] | | CAS: | 152329-44-7 | | MF: | C11H9BrZn | | MW: | 286.48 | | EINECS: | | | Product Categories: | Alkyl;Organozinc Halides;Reike and Organozinc Reagents | | Mol File: | 152329-44-7.mol |  |
| | (2-NAPHTHYL)METHYLZINC BROMIDE Chemical Properties |
| density | 0.978 g/mL at 25 °C | | Fp | -17 °C | | storage temp. | 2-8°C | | InChI | 1S/C11H9.BrH.Zn/c1-9-6-7-10-4-2-3-5-11(10)8-9;;/h2-8H,1H2;1H;/q;;+1/p-1 | | InChIKey | IKDINBHMSAHXCA-UHFFFAOYSA-M | | SMILES | Br[Zn]Cc1ccc2ccccc2c1 |
| | (2-NAPHTHYL)METHYLZINC BROMIDE Usage And Synthesis |
| Uses | (2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:
- 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
- (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.
| | General Description | (2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst. |
| | (2-NAPHTHYL)METHYLZINC BROMIDE Preparation Products And Raw materials |
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