4,4-(1,4-亚苯基)双(2,2:6,2-四吡啶)
| 中文名称 | 4,4-(1,4-亚苯基)双(2,2:6,2-四吡啶) |
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| 中文同义词 | 4,4-(1,4-亚苯基)双(2,2:6,2-四吡啶);4′,4′′′′-(1,4-亚苯基)二(2,2′:6′,2′′-三联吡啶);1,4-双(2,2':6',2-三联吡啶-4'-基)苯;1,4-二(2,2':6',2''-三联吡啶-4'-基)苯;1,4-双(2,2':6',2"-三联吡啶-4'-基)苯;4',4''''-(1,4-亚苯基)二(2,2':6',2''-三联吡啶);4鈥?4鈥测€测€测€?(1,4-PHENYLENE)BIS(2,2鈥?6鈥?2鈥测€?TERPYRIDINE);1,4-二[[2,2':6',2''-三联吡啶]-4'-基]苯 |
| 英文名称 | 4',4''''-(1,4-Phenylene)bis(2,2':6',2''-terpyridine) |
| 英文同义词 | 1,4-Bis(2,2':6',2''-terpyridin-4'-yl)benzene;4`,4````-(1,4-Phenylene)bis(2,2`:6`,2``-terpyridine),96%;1,4-bis[2,2':6',2''-terpyridine-4'-yl]benzene;1,4-Di([2,2':6',2''-terpyridin]-4'-yl)benzene;2,2':6',2''-Terpyridine, 4',4''''-(1,4-phenylene)bis-;1,4-bis(4'-phenyl-2,2':6',2''-terpyridin-4'-yl)benzene;4-{4-[2,6-BIS(PYRIDIN-2-YL)PYRIDIN-4-YL]PHENYL}-2,6-BIS(PYRIDIN-2-YL)PYRIDINE;4-[4-(2,6-dipyridin-2-ylpyridin-4-yl)phenyl]-2,6-dipyridin-2-ylpyridine |
| CAS号 | 146406-75-9 |
| 分子式 | C36H24N6 |
| 分子量 | 540.62 |
| EINECS号 | |
| 相关类别 | 溶剂;吡啶;通用试剂;合成材料中间体;2,2':6',2"-三联吡啶;Heterocyclic Compounds;C9 to C46;Heterocyclic Building Blocks;Pyridines;有机试剂 |
| Mol文件 | 146406-75-9.mol |
| 结构式 |  |
4,4-(1,4-亚苯基)双(2,2:6,2-四吡啶) 性质
| 熔点 | 340 °C (dec.)(lit.) |
|---|---|
| 沸点 | 727.8±55.0 °C(Predicted) |
| 密度 | 1.227±0.06 g/cm3(Predicted) |
| 储存条件 | Inert atmosphere,Room Temperature |
| 形态 | 粉末晶体 |
| 酸度系数(pKa) | 4.73±0.22(Predicted) |
| 颜色 | 白色到黄色到橙色 |
| 最大波长(λmax) | 292nm(CH2Cl2)(lit.) |
| InChIKey | NXMHYAQTBVTLRK-UHFFFAOYSA-N |
| SMILES | C1(C2C=C(C3=NC=CC=C3)N=C(C3=NC=CC=C3)C=2)=CC=C(C2C=C(C3=NC=CC=C3)N=C(C3=NC=CC=C3)C=2)C=C1 |
可作为配体用于合成MOF材料：Cu(terpy)4,4-(1,4-亚苯基)双(2,2:6,2-四吡啶)可用作有机合成中间体和医药中间体，主要用于实验室研发过程和化工生产过程中。
[2] Kinetic Studies of the Coordination of Mono- and Ditopic Ligands with First Row Transition Metal Ions. https://doi.org/10.1021/acs.inorgchem.5b02931
[3] Synthesis of Cu(II)-Organophosphonate Framework with Predefined Void Spaces. https://doi.org/10.1021/acs.cgd.5b01319
[4] Three-Dimensional Fe(II)-based Metallo-Supramolecular Polymers with Electrochromic Properties of Quick Switching, Large Contrast, and High Coloration Efficiency. https://doi.org/10.1021/am5010859
参考文献
[1] Multinucleating 2,2' : 6',2''-terpyridine ligands as building blocks for the assembly of co-ordination polymers and oligomers. https://doi.org/10.1039/DT9920003467
[2] Kinetic Studies of the Coordination of Mono- and Ditopic Ligands with First Row Transition Metal Ions. https://doi.org/10.1021/acs.inorgchem.5b02931
[3] Synthesis of Cu(II)-Organophosphonate Framework with Predefined Void Spaces. https://doi.org/10.1021/acs.cgd.5b01319
[4] Three-Dimensional Fe(II)-based Metallo-Supramolecular Polymers with Electrochromic Properties of Quick Switching, Large Contrast, and High Coloration Efficiency. https://doi.org/10.1021/am5010859
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| 更新日期 | 产品编号 | 产品名称 | CAS号 | 包装 | 价格 |
|---|---|---|---|---|---|
| 2026/06/06 | B4194 | 1,4-二[[2,2':6',2''-三联吡啶]-4'-基]苯 1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene | 146406-75-9 | 200mg | 250元 |
| 2026/06/06 | B4194 | 1,4-二[[2,2':6',2''-三联吡啶]-4'-基]苯 1,4-Di[[2,2':6',2''-terpyridin]-4'-yl]benzene | 146406-75-9 | 1g | 920元 |