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SILVER BROMIDE

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SILVER BROMIDE Basic information
Product Name:SILVER BROMIDE
Synonyms:SILVER BROMIDE;SILVER(I) BROMIDE;SILVER BROMIDE 99.999%;Silverbromide,Premion,99.999%(metalsbasis);Silver bromide, Premion(R), 99.998% (metals basis);SILVER BROMIDE PURIFIED;Silverbromide(99.9%-Ag);silver bromide, premion
CAS:7785-23-1
MF:AgBr
MW:187.77
EINECS:232-076-8
Product Categories:metal halide;Inorganics;Catalysis and Inorganic Chemistry;Chemical Synthesis;Silver;SilverMetal and Ceramic Science;Crystal Grade Inorganics;Metal and Ceramic Science;Salts;Silver Salts
Mol File:7785-23-1.mol
SILVER BROMIDE Structure
SILVER BROMIDE Chemical Properties
Melting point 432 °C (lit.)
Boiling point 700 °C
density 6.473 g/mL at 25 °C (lit.)
storage temp. Room Temperature
solubility insoluble in H2O, acid solutions, ethanol
form Powder
color Pale Yellow
Specific Gravity6.473
Water Solubility soluble in alkali cyanide solutions. Partially soluble in ammonia. Insoluble in alcohol and acids. Practically insoluble in water.
Crystal StructureCubic, Sphalerite Structure - Space Group F(-4)3m
Sensitive Light Sensitive
Merck 14,8506
Solubility Product Constant (Ksp)pKsp: 12.3(25°C)
Dielectric constant12.2(0.0℃)
Stability:Stability Darkens in light
Major ApplicationPEM fuel cells
material synthesis precursor
InChI1S/Ag.BrH/h;1H/q+1;/p-1
InChIKeyADZWSOLPGZMUMY-UHFFFAOYSA-M
SMILESBr[Ag]
Hardness, Mohs2.5
CAS DataBase Reference7785-23-1(CAS DataBase Reference)
EPA Substance Registry SystemSilver bromide (AgBr) (7785-23-1)
Safety Information
Hazard Codes Xi
Safety Statements 22-24/25
WGK Germany 3
8
Hazard Note Irritant
TSCA TSCA listed
HazardClass 9
HS Code 2843290000
Storage Class13 - Non Combustible Solids
Hazard ClassificationsAquatic Acute 1
Aquatic Chronic 1
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
SILVER BROMIDE Usage And Synthesis
Chemical PropertiesSilver bromide, AgBr, is pale yellow crystals or powder, that darken on exposure to light, finally turning black and soluble in potassium bromide, potassium cyanide, and sodium thiosulfate solutions, only very slightly soluble in ammonia water, insoluble in water, and light sensitive. Derivation is through silver nitrate dissolving in water and a solution ofalkali bromide added slowly. The precipitated silver bromide is washed repeatedly with hotwater. The operation must be carried on in a darkroom under a ruby-red light. Used in photographic film and plates, photochromic glass and as a laboratory reagent.
Physical propertiesYellow cubic crystals or powder; refractive index 2.253; darkens on exposure to light; Mohs hardness 2.5; density 6.47g/cm3; melts at 432°C; vaporizes at 1,502°C; insoluble in water, alcohol, and most acids; slightly soluble in dilute ammonia and ammonium carbonate solutions; sparingly soluble in concentrated ammonia solution (0.33 g/100mL 10% ammonia solution at 12°C);soluble in alkali cyanide solutions.
UsesIn photography.
UsesSilver Bromide is used in the spectroscopic study of silver halides in montmorillonite and their antibacterial activity, also used in the antimicrobial compositions for use in wound care products.
UsesA yellowish powder made by the combination of any soluble bromide with silver nitrate. Silver bromide could also be formed by exposing metallic silver to the fumes of bromine as in the daguerreotype process. It is soluble in sodium thiosulfate, potassium bromide, and potassium cyanide solutions. Silver bromides were secondary halides for the paper negative processes, albumen negative process, and wet or preserved collodion processes. Silver bromides were the primary halides for the silver bromide collodion emulsion negative and the silver bromide gelatin emulsion processes. Silver bromide is the most photosensitive silver halide.
PreparationSilver bromide is prepared by double decomposition reaction. An aqueous solution of alkali bromide, such as sodium or potassium bromide, is slowly added to an aqueous solution of silver nitrate:
Ag+ (aq) + Brˉ (aq) → AgBr(s)
The precipitate is washed repeatedly with hot water. Preparation should be in a dark room under a ruby red light.
Flammability and ExplosibilityNon flammable
Purification MethodsIt is insoluble in dilute HNO3 or dilute NH3 but is soluble in conc NH3. Store it in the dark.
Tag:SILVER BROMIDE(7785-23-1) Related Product Information
Barium sulfate SILVER(I) SULFIDE Cupric hydroxide NEODYMIUM(III) BROMIDE HYDRATE Zinc bromide Sodium thiosulfate pentahydrate Sodium bromide Magnesium oxide Ethyl acetate Potassium sulfate Zinc oxide Barium nitrate Iron hydroxide Ferric chloride ETHYLENE Poly(methyl methacrylate) TITANIUM(IV) BROMIDE Magnesium bromide hexahydrate

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