Tris(triphenylphosphinegold)oxonium tetrafluoroborate

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Tris(triphenylphosphinegold)oxonium tetrafluoroborate Basic information
Reaction
Product Name:Tris(triphenylphosphinegold)oxonium tetrafluoroborate
Synonyms:TRIS[TRIPHENYLPHOSPHINEGOLD (I)]OXONIUM TETRAFLUOROBORATE;TRIS(TRIPHENYLPHOSPHINEGOLD)OXOIUM TETRAFLUOROBORATE;TRIS(TRIPHENYLPHOSPHINEGOLD)OXONIUM TET&;Tris[triphenylphosphinegold(I)]oxoniumtetrafluoroborate,98%;Tris(triphenylphosphineaurio)oxonium tetrafluoroborate;Oxotris((triphenylphosphine)gold) tetrafluoroborate;Oxotris(triphenylphosphine)trigold tetrafluoroborate;Tris[(triphenylphosphino)aurio(I)]oxonium tetrafluoroborate
CAS:53317-87-6
MF:C54H45Au3BF4OP3
MW:1480.56
EINECS:
Product Categories:Au;Catalysis and Inorganic Chemistry;Chemical Synthesis;Gold Catalysis;Gold Catalysts;GoldCatalysis and Inorganic Chemistry;metal phosphine complex
Mol File:53317-87-6.mol
Tris(triphenylphosphinegold)oxonium tetrafluoroborate Structure
Tris(triphenylphosphinegold)oxonium tetrafluoroborate Chemical Properties
Melting point 207°C (dec.)
form Powder
color off-white
Sensitive air sensitive
InChI1S/3C18H15P.3Au.BF4.O/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;;2-1(3,4)5;/h3*1-15H;;;;;/q;;;;;;-1;+1
InChIKeyHTZIGJMQHZNAQD-UHFFFAOYSA-N
SMILES[Au][O+]([Au])[Au].F[B-](F)(F)F.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
Tris(triphenylphosphinegold)oxonium tetrafluoroborate Usage And Synthesis
Reaction
  1. Catalyst for the Claisen Rearrangement of propargyl vinyl ethers. Chirality is efficiently transferred.
  2. Catalyst for the oxidative cleavage of a Carbon-Carbon triple bond in (Z)-Enynols and cyclization.
Reactions of 53317-87-6
UsesUsed in a variety of gold catalyzed reactions including propargyl Claisen rearrangements.
reaction suitabilitycore: gold
reagent type: catalyst
Tris(triphenylphosphinegold)oxonium tetrafluoroborate Preparation Products And Raw materials
Tag:Tris(triphenylphosphinegold)oxonium tetrafluoroborate(53317-87-6) Related Product Information
IMINOCTADINE TRIS(ALBESILATE) Tris(triphenylphosphinegold)oxonium tetrafluoroborate Borane-triphenylphosphine complex Trimethyloxonium Tetrafluoroborate Chlorotris(triphenylphosphine)cobalt(I) Bromotris(triphenylphosphine)rhodium(I)