ETHYL (DIPHENYLMETHYLSILYL)ACETATE

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Suppliers list

Company Name:	Sigma-Aldrich
Tel:	021-61415566 800-8193336
Email:	orderCN@merckgroup.com
Products Intro:	Product Name:2-Fluoro-6-iodobenzoic acid CAS:13950-57-7 Purity:2-Fluoro-6-iodobenzoic acid Package:5ML Remarks:43125-5ML

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Basic information

Product Name:	ETHYL (DIPHENYLMETHYLSILYL)ACETATE
Synonyms:	ETHYL (DIPHENYLMETHYLSILYL)ACETATE;ethyl (methyldiphenylsilyl)acetate;2-(Methyldiphenylsilyl)acetic acid ethyl ester
CAS:	13950-57-7
MF:	C17H20O2Si
MW:	284.425
EINECS:
Product Categories:
Mol File:	13950-57-7.mol

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Chemical Properties

Safety Information

MSDS Information

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Usage And Synthesis

Physical properties	clear to light yellow liquids.
Uses	vinyl 1,1-dication synthetic equivalent in reactions with Grignard reagents; reagent for Peterson synthesis of α,β-un saturated esters.
Preparation	whereas the direct silylation of the lithium enolate of an ester normally results in the formation of a mixture of the α-silyl ester and the corresponding silyl ketene acetal, the same reaction with methyldiphenylchlorosilane gives exclusively the α-methyldiphenylsilyl ester. This direct C-silylation is the best general route to α-silyl esters.
Purification Methods	ETHYL (DIPHENYLMETHYLSILYL)ACETATE can be best purified by silica gel chromatography. The esters can be distilled through a suitable short path apparatus.

ETHYL (DIPHENYLMETHYLSILYL)ACETATE Preparation Products And Raw materials

Preparation Products

Tag:ETHYL (DIPHENYLMETHYLSILYL)ACETATE(13950-57-7) Related Product Information

PHENYLTRIMETHYLSILANE ETHYL (DIPHENYLMETHYLSILYL)ACETATE (TRIMETHYLSILYL)ACETIC ACID DIMETHYLPHENYLSILYLACETIC ACID 2-(METHYLDIPHENYLSILYL)ETHANOL Diphenylsilane 2-(Trimethylsilyl)ethanol METHYL (TRIMETHYLSILYL)ACETATE DIMETHYLDIPHENYLSILANE Ethyl (trimethylsilyl)acetate

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