4,5-二氢芘-4,5-二酮
| 中文名称 | 4,5-二氢芘-4,5-二酮 |
|---|---|
| 中文同义词 | 芘-4,5-二酮;4,5-二氢芘-4,5-二酮 |
| 英文名称 | PYRENE-4,5-QUINONE |
| 英文同义词 | PYRENE-4,5-QUINONE;4,5-Pyrenedione;Pyrenedione;pyrene-4,5-dione - [P87108] |
| CAS号 | 6217-22-7 |
| 分子式 | C16H8O2 |
| 分子量 | 232.23 |
| EINECS号 | |
| 相关类别 | 有机化学;科研材料中间体 |
| Mol文件 | 6217-22-7.mol |
| 结构式 |  |
4,5-二氢芘-4,5-二酮 性质
| 熔点 | 310 °C |
|---|---|
| 沸点 | 467.6±12.0 °C(Predicted) |
| 密度 | 1.433±0.06 g/cm3(Predicted) |
| 储存条件 | 2-8°C |
| 溶解度 | 可溶于氯仿（少许）、甲醇（少许） |
| 形态 | 固体 |
| 颜色 | 浅棕色至深棕色 |
| InChI | InChI=1S/C16H8O2/c17-15-11-5-1-3-9-7-8-10-4-2-6-12(16(15)18)14(10)13(9)11/h1-8H |
| InChIKey | JKCATVQPENLMQJ-UHFFFAOYSA-N |
| SMILES | C1=C2C3C4C(C=C2)=CC=CC=4C(=O)C(=O)C=3C=C1 |
可作为配体用于合成MOF材料
[2] From Armchair to Zigzag Peripheries in Nanographenes. https://doi.org/10.1021/ja062026h
[3] Highly selective photomediated 1,4-radical addition to o-quinones controlled by a self-assembled cage. https://doi.org/10.1002/anie.200705139
参考文献
[1] Ruthenium(III) Chloride Catalyzed Oxidation of Pyrene and 2,7-Disubstituted Pyrenes: An Efficient, One-Step Synthesis of Pyrene-4,5-diones and Pyrene-4,5,9,10-tetraones. https://doi.org/10.1021/jo048509q
[2] From Armchair to Zigzag Peripheries in Nanographenes. https://doi.org/10.1021/ja062026h
[3] Highly selective photomediated 1,4-radical addition to o-quinones controlled by a self-assembled cage. https://doi.org/10.1002/anie.200705139