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Energy Chemical
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Product Name:Ethyl 2-(triMethylsilylMethyl)acrylate
CAS:74976-84-4
Purity:97% Package:1G
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| Company Name: |
Syntechem Co.,Ltd
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info@syntechem.com |
| Products Intro: |
Product Name:ethyl 2-((triMethylsilyl)Methyl)acrylate
CAS:74976-84-4
Purity:97% Package:1g;5g;25g;100g;250g;1kg;5kg;10kg;25kg Remarks:we offer low price custom synthesis and contract manufacturing
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ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE manufacturers
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| | ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE Basic information |
| Product Name: | ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE | | Synonyms: | 2-(TRIMETHYLSILYLMETHYL)ACRYLIC ACID ETHYL ESTER;ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE;ETHYL 2-(TRIMETHYLSILYLMETHYL)PROPENOATE;2-(Trimethylsilylmethyl)acrylic acid ethyl ester, Ethyl 2-(trimethylsilylmethyl)propenoate;2-Ethoxycarbonylallyltrimethylsilane;2-Propenoic acid, 2-[(trimethylsilyl)methyl]-, ethyl ester | | CAS: | 74976-84-4 | | MF: | C9H18O2Si | | MW: | 186.32 | | EINECS: | | | Product Categories: | | | Mol File: | 74976-84-4.mol |  |
| | ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE Chemical Properties |
| Boiling point | 70-72 °C/10 mmHg (lit.) | | density | 0.897 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.438(lit.) | | Fp | 140 °F | | storage temp. | 2-8°C | | form | liquid | | BRN | 4658894 | | InChI | 1S/C9H18O2Si/c1-6-11-9(10)8(2)7-12(3,4)5/h2,6-7H2,1,3-5H3 | | InChIKey | HSEYTIDQGJXPIF-UHFFFAOYSA-N | | SMILES | CCOC(=O)C(=C)C[Si](C)(C)C |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | RIDADR | 1993 | | WGK Germany | 3 | | F | 10-21 | | HazardClass | 3.2 | | PackingGroup | III | | Storage Class | 10 - Combustible liquids | | Hazard Classifications | Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| | ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE Usage And Synthesis |
| Uses | 2-Ethoxycarbonylallyltrimethylsilane is used for 2-ethoxycarbonylallylation of aldehydes and acetals; the allylation products are useful precursors to α-
methylene-γ-butyrolactones; precursor of allyl cation equivalents for [3 + 2] and [3 + 4] cycloadditions. | | Preparation | Preparative Methods of 2-Ethoxycarbonylallyltrimethylsilane: a three-step synthesis from Diethyl Malonate has been reported. t-Butyl and
trimethylsilyl esters are also prepared by this method. Syntheses from ethyl diethylphosphonoacetate and
ethyl α-bromoacrylate also have been reported, but the simplest procedure involves the reaction of
ethoxalyl chloride with two equivalents of Trimethylsilylmethylmagnesium Chloride followed by
treatment with Thionyl Chloride (53% yield). The CeIII-mediated reaction of
trimethylsilylmethylmagnesium chloride with Diethyl Oxalate is also reported to give 2-
ethoxycarbonylallyltrimethylsilane in 45% yield. | | storage | 2-Ethoxycarbonylallyltrimethylsilane can be stored in a glass bottle. |
| | ETHYL 2-(TRIMETHYLSILYLMETHYL)ACRYLATE Preparation Products And Raw materials |
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