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(3-Bromophenyl)thiourea

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(3-Bromophenyl)thiourea Basic information
Structure
Product Name:(3-Bromophenyl)thiourea
Synonyms:N-(3-BROMOPHENYL)THIOUREA;1-(3-BROMOPHENYL)-2-THIOUREA;Thiourea, N-(3-bromophenyl)-;(3-bromophenyl)thiourea;m-Bromophenylthiourea;1-(3-bromophenyl)thiourea
CAS:21327-14-0
MF:C7H7BrN2S
MW:231.11
EINECS:
Product Categories:
Mol File:21327-14-0.mol
(3-Bromophenyl)thiourea Structure
(3-Bromophenyl)thiourea Chemical Properties
Melting point 150 °C
Boiling point 314.7±44.0 °C(Predicted)
density 1.728±0.06 g/cm3(Predicted)
storage temp. 2-8°C(protect from light)
solubility DMSO (Slightly), Methanol (Slightly)
form powder to crystal
pka13.04±0.70(Predicted)
color White to Orange to Green
Safety Information
Risk Statements 36/37/38-43
Safety Statements 26-36/37/39-36/37
RIDADR 2811
HS Code 2930.90.2900
HazardClass 6.1
PackingGroup III
MSDS Information
(3-Bromophenyl)thiourea Usage And Synthesis
Structure(3-Bromophenyl)thiourea, C7H7BrN2S, the thio­urea moiety is nearly planar (r.m.s. deviation = 0.004 Å) and it forms a dihedral angle of 66.72 (15)° with the benzene ring. The C—N—C—N2 torsion angle is 15.1 (4)°. In the crystal, mol­ecules are linked via N—H⋯S and N—H⋯N hydrogen bonds into sheets lying parallel to (101)[1].
1-(3-BROMOPHENYL)-2-THIOUREA
References[1] Fun, Hoong-Kun et al. “1-(3-Bromo-phen-yl)thio-urea.” Acta crystallographica. Section E, Structure reports online vol. 68,Pt 8 (2012): o2462. doi:10.1107/S1600536812031601
(3-Bromophenyl)thiourea Preparation Products And Raw materials
Preparation Products2-Amino-7-bromobenzothiazole-->2-Amino-5-bromobenzothiazole-->2-Amino-6-bromobenzothiazole
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