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Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate

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Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate manufacturers

Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate Basic information
Reaction
Product Name:Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate
Synonyms:TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(I) HEXACHLOROPHOSPHATE;TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHENIUM(I)HEXAFLUOROPHOSPHATE;Trisacetonitrilecyclopentadienylrutheniumhexachlorophosphate;TRIS(ACETONITRILE)CYCLOPENTADIENYLRUTHE&;Tris(acetonitrile)cyclopentadienylruthenium(II)hexafluorophosphate,min.98%;Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate, min. 98%;Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate,98%;Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
CAS:80049-61-2
MF:C11H14F6N3PRu5*
MW:434.28
EINECS:
Product Categories:Ru;organometallic complex
Mol File:80049-61-2.mol
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate Structure
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate Chemical Properties
Melting point 117-118°C
storage temp. 2-8°C
form Powder
color Yellow to orange or brown
Sensitive Air & Moisture Sensitive
InChI1S/C5H5.3C2H3N.F6P.Ru/c1-2-4-5-3-1;3*1-2-3;1-7(2,3,4,5)6;/h1-5H;3*1H3;;/q;;;;-1;+1
InChIKeyHJQVFVSAQOQXRG-UHFFFAOYSA-N
SMILES[Ru+].CC#N.CC#N.CC#N.[CH]1[CH][CH][CH][CH]1.F[P-](F)(F)(F)(F)F
Safety Information
Hazard Codes Xi
Risk Statements 20/21/22-36/37/38
Safety Statements 22-36/37/39-26
WGK Germany 3
TSCA No
HS Code 28439090
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate Usage And Synthesis
Reaction
  1. Catalyst used for the coupling of allene with activated olefines to form 1,3-diene.
  2. Catalyst used for the dimerization of propargyl alcohols.
  3. Catalyst used in the Trost's ruthenium-catalyzed ene-yne cross-coupling reaction.
  4. Catalyst for asymmetric cyclization of ω-hydroxy allyl alcohols to give α-alkenyl cyclic ethers.
  5. Catalyst for synthesis of furans from bis(alkynes) and DMSO.
Reactions of 80049-61-2_1
Reactions of 80049-61-2_2
Chemical PropertiesYellow to orange or brown powder
UsesTris(acetonitrile)cyclopentadienylruthenium(II) Hexafluorophosphate is a catalyst, and catalyzes the reaction of diynes with aldehydes and N,N-dimethylformamide and also catalyzes other organic reactions.
reaction suitabilitycore: ruthenium
reagent type: catalyst
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate Preparation Products And Raw materials
Tag:Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate(80049-61-2) Related Product Information
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