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| | Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Basic information | | Reactions |
| Product Name: | Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate | | Synonyms: | TRIS-(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM(II) HEXAFLUOROPHOSPHATE;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II)hexafluorophosphate,min.98%;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate, min. 98%;Tris(acetonitrile)pentaMethylcyclopentadienylrutheniuM(II) hexafluorophosphate,98%;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(i)hexafluorophosphate,min.;Tris(acetonitrile)(eta5-pentamethylcyclopentadienyl)ruthenium hexafluorophosphate;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II);Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II)
Hexafluorophosphate Powder | | CAS: | 99604-67-8 | | MF: | C16H24F6N3PRu | | MW: | 504.42 | | EINECS: | | | Product Categories: | metallocene;Ru | | Mol File: | 99604-67-8.mol |  |
| | Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Chemical Properties |
| storage temp. | 2-8°C | | form | Powder | | color | yellow orange | | Sensitive | air sensitive, store cold | | InChI | 1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1 | | InChIKey | IYEMDYLFXFMECZ-UHFFFAOYSA-N | | SMILES | [Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C | | CAS DataBase Reference | 99604-67-8 |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26 | | WGK Germany | 3 | | Storage Class | 11 - Combustible Solids | | Hazard Classifications | Eye Irrit. 2 Skin Irrit. 2 STOT SE 3 |
| | Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Usage And Synthesis |
| Reactions |
- Useful catalyst for the hydrosilylation of internal and terminal alkynes. The reaction has also been extended to intramolecular hydrosilylation.
- Catalyst for the cycloisomerization of diynes.
- Catalyst for synthesis of furans from bis(alkynes) and DMSO.
| | Uses | Hydrosilylation Catalysts | | reaction suitability | core: ruthenium reagent type: catalyst |
| | Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Preparation Products And Raw materials |
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