Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate

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Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Basic information
Reactions
Product Name:Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate
Synonyms:TRIS-(ACETONITRILE)PENTAMETHYLCYCLOPENTADIENYLRUTHENIUM(II) HEXAFLUOROPHOSPHATE;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II)hexafluorophosphate,min.98%;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate, min. 98%;Tris(acetonitrile)pentaMethylcyclopentadienylrutheniuM(II) hexafluorophosphate,98%;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(i)hexafluorophosphate,min.;Tris(acetonitrile)(eta5-pentamethylcyclopentadienyl)ruthenium hexafluorophosphate;Tris(acetonitrile)pentamethylcyclopentadienylruthenium(II);Pentamethylcyclopentadienyltris (acetonitrile)ruthenium(II) Hexafluorophosphate Powder
CAS:99604-67-8
MF:C16H24F6N3PRu
MW:504.42
EINECS:
Product Categories:metallocene;Ru
Mol File:99604-67-8.mol
Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Structure
Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Chemical Properties
storage temp. 2-8°C
form Powder
color yellow orange
Sensitive air sensitive, store cold
InChI1S/C10H16.3C2H3N.F6P.Ru/c1-6-7(2)9(4)10(5)8(6)3;3*1-2-3;1-7(2,3,4,5)6;/h6H,1-5H3;3*1H3;;/q;;;;-1;+1
InChIKeyIYEMDYLFXFMECZ-UHFFFAOYSA-N
SMILES[Ru+].CC#N.CC#N.CC#N.F[P-](F)(F)(F)(F)F.CC1C(C)=C(C)C(C)=C1C
CAS DataBase Reference99604-67-8
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
Storage Class11 - Combustible Solids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Usage And Synthesis
Reactions
  • Useful catalyst for the hydrosilylation of internal and terminal alkynes. The reaction has also been extended to intramolecular hydrosilylation.
  • Catalyst for the cycloisomerization of diynes.
  • Catalyst for synthesis of furans from bis(alkynes) and DMSO.
Reactions of 99604-67-8
UsesHydrosilylation Catalysts
reaction suitabilitycore: ruthenium
reagent type: catalyst
Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate Preparation Products And Raw materials
Tag:Tris(acetonitrile)pentamethylcyclopentadienylruthenium (I) hexafluorophosphate(99604-67-8) Related Product Information
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