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DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE

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DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE Basic information
Product Name:DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE
Synonyms:Phosphonic acid, (2,2-diethoxyethyl)-, diethyl ester;DIETHYL PHOSPHONOACETALDEHYDE DIETHYL ACETAL;DIETHYL PHOSPHONACETALDEHYDE DIETHYL ACETAL;DIETHYL 2,2-DIETHOXETHYLPHOSPHONATE;DIETHYL 2,2-DIETHOXY-ETHANEPHOSPHONATE;DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE;AURORA KA-1450;Diethyl phosphonoacetaldehyde diethyl acetal, 90%, tech.
CAS:7598-61-0
MF:C10H23O5P
MW:254.26
EINECS:231-504-0
Product Categories:Wittig Reagents;Horner-Emmons Reaction;Synthetic Organic Chemistry;Wittig & Horner-Emmons Reaction
Mol File:7598-61-0.mol
DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE Structure
DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE Chemical Properties
Boiling point 146-149 °C14 mm Hg(lit.)
density 1.052 g/mL at 25 °C(lit.)
refractive index n20/D 1.430(lit.)
Fp >230 °F
storage temp. 2-8°C
solubility Chloroform, Dichloromethane
form Oil
color Colourless
Water Solubility Soluble in chloroform and dichloromethane. Not miscible or difficult to mix in water.
Sensitive Moisture Sensitive
BRN 1785614
InChI1S/C10H23O5P/c1-5-12-10(13-6-2)9-16(11,14-7-3)15-8-4/h10H,5-9H2,1-4H3
InChIKeyLUQYELQXRPNKRY-UHFFFAOYSA-N
SMILESCCOC(CP(=O)(OCC)OCC)OCC
CAS DataBase Reference7598-61-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
RIDADR UN2810
WGK Germany 3
F 21
HazardClass 6.1
HS Code 29319090
Storage Class10 - Combustible liquids
Hazard ClassificationsEye Irrit. 2
Skin Irrit. 2
STOT SE 3
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE Usage And Synthesis
Chemical PropertiesColourless Oil
UsesDiethyl 2,2-diethoxyethylphosphonate can be used as a useful wittig reagent.
UsesDiethyl 2,2-diethoxyethylphosphonate is used reactant for synthesis of α,β-alkenal derivatives by two-carbon homologation, lower rim-phosphonylated rexorcinol calix[4]arenes by condensation reactions, α-Phosphovinyl radicals via a radical trapping sequence, inhibitors of reverse transcriptase via 1,3-dipolar cycloadditions and for Friedel-Crafts reactions.
UsesReactant for synthesis of:
  • α,β-Alkenal derivatives by two-carbon homologation
  • Lower rim-phosphonylated rexorcinol calix[4]arenes by condensation reactions
  • α-Phosphovinyl radicals via a radical trapping sequence
  • Inhibitors of reverse transcriptase via 1,3-dipolar cycloadditions

Reactant for Friedel-Crafts reactions
reaction suitabilityreaction type: C-C Bond Formation
DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE Preparation Products And Raw materials
Preparation ProductsTetraethyl ethylenediphosphonate
Tag:DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE(7598-61-0) Related Product Information
Dimethyl 2-hydroxyethylphosphonate Methyldiethoxyphosphine Dimethyl methylphosphonate DIETHYL 2,2-DIETHOXYETHYLPHOSPHONATE Dimethyl ethylphosphonite Diethyl ethylphosphonate Ethylphosphonic acid Methylphosphonic acid DIETHYL PHOSPHATE Diethyl methylphosphonate DIMETHYL ETHYLPHOSPHONATE Ethyl methylphosphonic acid Diethyl 2,2-dimethoxyethylphosphonate 2-Hydroxyethyl phosphonic acid Ethyl methylphosphinate Ethyl hydrogen ethylphosphonate Diethyl ethylphosphonite METHYL METHYLPHOSPHONIC ACID