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| | Nickel chloride, dimethoxyethane adduct Basic information | | Synthesis |
| Product Name: | Nickel chloride, dimethoxyethane adduct | | Synonyms: | Nickel(II) chloride ethylene glycol dimethyl ether complex;Nickel(II) chloride, dimethoxyethane adduct, min. 97%;Nickel(II) chloride ethylene glycol diMethyl ether coMplex 98%;Dichloro(1,2-dimethoxyethane)nickel;NICKEL(II)CHLORIDE,DIMETHOXYETHANEADDUCT,MIN.97%;Nickel(II) chloride ethylene glycol dimethyl;Nickel(II) Chloride Dimethoxyethane Complex;oride ethyL | | CAS: | 29046-78-4 | | MF: | C4H10Cl2NiO2 | | MW: | 219.72 | | EINECS: | | | Product Categories: | metal halide | | Mol File: | 29046-78-4.mol |  |
| | Nickel chloride, dimethoxyethane adduct Chemical Properties |
| Melting point | >300 °C | | storage temp. | Inert atmosphere,Room Temperature | | form | Powder | | color | yellow | | Relative polarity | 0.231 | | Sensitive | moisture sensitive | | InChI | 1S/C4H10O2.2ClH.Ni/c1-5-3-4-6-2;;;/h3-4H2,1-2H3;2*1H;/q;;;+2/p-2 | | InChIKey | OCMNCWNTDDVHFK-UHFFFAOYSA-L | | SMILES | Cl[Ni]Cl.COCCOC |
| | Nickel chloride, dimethoxyethane adduct Usage And Synthesis |
| Synthesis | 
NiCl2 (100 g, 771.6 mmol) was dissolved in a mixture of 300 mL methanol and 50 mL trimethyl orthoformate and refluxed with stirring overnight. After the reaction was complete, unreacted NiCl2 was removed by filtration, and 80% of the solution was removed under reduced pressure to obtain a green gel. This gel was dissolved in a minimal amount of methanol, and 300 mL DME was added. The solution was refluxed with stirring overnight. A yellow powder precipitate of NICKEL CHLORIDE, DIMETHOXYETHANE ADDUCT was separated by tube filtration. The powder was washed with pentane and dried under a nitrogen stream. | | Uses | Nickel(II) chloride ethylene glycol dimethyl ether is commonly used as a catalyst for the synthesis of various organic compounds. | | Uses | Nickel(II) chloride ethylene glycol dimethyl ether complex can be used:
- As a catalyst for the borylation of racemic benzylic chloride to synthesize enantioenriched benzylic boronic esters.
- As a promoter for the trifluoromethylation of alkyl iodides to synthesize broad range of alkyl-CF3 compounds.
- For the synthesis of nickel bis(benzimidazol-2-ylidene) pincer complexes which can be used for electrocatalytic reduction of CO2 to CO.
- As a Lewis acid catalyst for C-acylation β-ketoesters through photoactivation by visible light.
| | reaction suitability | core: nickel
reagent type: catalyst |
| | Nickel chloride, dimethoxyethane adduct Preparation Products And Raw materials |
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