PCN-222(H)金属有机骨架
| 中文名称 | PCN-222(H)金属有机骨架 |
|---|---|
| 中文同义词 | PCN-222(H)金属有机骨架;PCN-222(H)金属有机框架 |
| 英文名称 | Zirconium, octa-μ -hydroxyoctahydroxybis[μ-[4-[10,15,20-tris(4-carboxyphenyl)-21H,23H-porphin-5-yl]benzoato(4-)-κO:κO']]hexa- |
| 英文同义词 | Zirconium, octa-μ -hydroxyoctahydroxybis[μ-[4-[10,15,20-tris(4-carboxyphenyl)-21H,23H-porphin-5-yl]benzoato(4-)-κO:κO']]hexa-;PCN-222(H);PCN-222(Zr）;Octa-μ3-hydroxyoctahydroxybis[μ-[4-[10,15,20-tris(4-carboxyphenyl)-21H,23H-porphin-5-yl]benzoato(4-)-κO:κO']]hexazirconium;PCN-222(H） MOF-545 |
| CAS号 | 1403461-06-2 |
| 分子式 | C96H52N8O32Zr6 |
| 分子量 | 2376.84 |
| EINECS号 | |
| 相关类别 | MOF |
| Mol文件 | 1403461-06-2.mol |
| 结构式 |  |
PCN-222(H)金属有机骨架 性质
| 配位金属 | Zr |
| 配体 | 4-羧基苯基卟啉 |
| 孔径 | 3.7nm;1.3nm |
| 孔容 | 1.5cm3/g |
| 粒径 | 2um*50nm针状晶粒 |
| 比表面 | BET比表面2000m2/g |
参考文献
[1] Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts. https://doi.org/10.1002/ange.201204475
[2] Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks. https://doi.org/10.1021/ic300825s
[3] Selective Photooxidation of a Mustard-Gas Simulant Catalyzed by a Porphyrinic Metal–Organic Framework. https://doi.org/10.1002/anie.201503741
[4] Direct evidence of charge separation in a metal–organic framework: efficient and selective photocatalytic oxidative coupling of amines via charge and energy transfer. https://doi.org/10.1039/c7sc05296k
[5] Formulation of Metal−Organic Framework-Based Drug Carriers by Controlled Coordination of Methoxy PEG Phosphate: Boosting Colloidal Stability and Redispersibility. https://doi.org/10.1021/jacs.1c03943