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7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)-

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7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)- Basic information
Product Name:7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)-
Synonyms:7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)-;(2S)-2α-[1-Methyl-1-(β-D-glucopyranosyloxy)ethyl]-2,3-dihydro-7H-furo[3,2-g][1]benzopyran-7-one;(S)-2-[1-(β-D-Glucopyranosyloxy)-1-methylethyl]-2,3-dihydro-7H-furo[3,2-g][1]benzopyran-7-one;Marmesinin( Ammajin,Ammijin,Marmesinin,(-)-Marmesinin);7H-Furo[3,2-g][1]benzopyran-7-one, 2-[1-(β-D-glucopyranosyloxy)-1-methylethyl]-2,3-dihydro-, (2S)-;(2S)-2-[2-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxypropan-2-yl]-2,3-dihydrofuro[3,2-g]chromen-7-one;(-)-Marmesinin;Isorapigenin
CAS:495-30-7
MF:C20H24O9
MW:408.4
EINECS:
Product Categories:
Mol File:495-30-7.mol
7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)- Structure
7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)- Chemical Properties
Melting point 259-260 °C (decomp)(Solv: water (7732-18-5))
Boiling point 657.1±55.0 °C(Predicted)
density 1.51±0.1 g/cm3(Predicted)
pka12.90±0.70(Predicted)
form Solid
color White to off-white
InChIKeyHXCGUCZXPFBNRD-YTLMEVRINA-N
SMILESC1(=O)OC2=CC3O[C@H](C(O[C@@H]4O[C@H](CO)[C@@H](O)[C@H](O)[C@H]4O)(C)C)CC=3C=C2C=C1 |&1:7,10,12,15,17,19,r|
Safety Information
MSDS Information
7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)- Usage And Synthesis
UsesMarmesinin ((-)-Marmesinin), a natural coumarin, is a biosynthetic precursor of psoralen and linear furanocoumarins. Marmesinin exhibits significant neuroprotective activities against glutamate-induced toxicity[1][2].
DefinitionChEBI: Marmesinin is a member of the class of psoralens that is (-)-marmesin in which the hydroxy hydrogen is replaced by a beta-D-glucosyl residue. It has a role as a plant metabolite, a P450 inhibitor and an antioxidant. It is a beta-D-glucoside, a member of psoralens and a monosaccharide derivative. It is functionally related to a nodakenetin.
References[1] ABU-MUSTAFA EA, et, al. Natural Coumarins. I. Marmesin and Marmesinin, Further Products from the Fruits of Ammi majus L. J. Org. Chem. 1961 Jan; 26 (1): 161-166.
[2] Kang SY, et, al. Neuroprotective coumarins from the root of Angelica gigas: structure-activity relationships. Arch Pharm Res. 2007 Nov;30(11):1368-73. DOI:10.1007/BF02977358
7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)- Preparation Products And Raw materials
Tag:7H-Furo(3,2-g)(1)benzopyran-7-one, 2-(1-(beta-D-glucopyranosyloxy)-1-m ethylethyl)-2,3-dihydro-, (S)-(495-30-7) Related Product Information
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