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| | 2-Bromo-4-tert-butylphenol Basic information |
| Product Name: | 2-Bromo-4-tert-butylphenol | | Synonyms: | Phenol, 2-bromo-4-(1,1-dimethylethyl)-;2-broMo-4-(1,1-diMethylethyl)-;AKOS BBB/374;4-TERT-BUTYL-2-BROMOPHENOL;2-Bromo-4-tert-butylphenol >;2-Bromo-4-t-butylphenol;2-Bromo-4-tert-butylphenol | | CAS: | 2198-66-5 | | MF: | C10H13BrO | | MW: | 229.11 | | EINECS: | 218-602-9 | | Product Categories: | | | Mol File: | 2198-66-5.mol |  |
| | 2-Bromo-4-tert-butylphenol Chemical Properties |
| Melting point | 51°C(lit.) | | Boiling point | 113°C/9mmHg(lit.) | | density | 1.341±0.06 g/cm3(Predicted) | | storage temp. | Sealed in dry,Room Temperature | | solubility | Chloroform (Slightly), Methanol (Slightly) | | form | Oil | | pka | 8.65±0.18(Predicted) | | color | Clear Colourless | | InChI | InChI=1S/C10H13BrO/c1-10(2,3)7-4-5-9(12)8(11)6-7/h4-6,12H,1-3H3 | | InChIKey | FFRLMQPMGIMHHQ-UHFFFAOYSA-N | | SMILES | C1(O)=CC=C(C(C)(C)C)C=C1Br |
| Hazard Codes | Xi | | HazardClass | IRRITANT | | HS Code | 2908190090 |
| | 2-Bromo-4-tert-butylphenol Usage And Synthesis |
| Chemical Properties | White crystalline | | Uses | 2-Bromo-4-tert-butylphenol is useful synthetic compound that can be used to prepare 2-Mesityl-4-tert-butylphenol. | | Synthesis | A method for the preparation of 2-bromo-4-tert-butylphenol, comprising the steps of S11. dissolving 1 mol 4-tert-butylphenol in 300-500 ml of acetic acid solution at room temperature, followed by adding 150-250 ml of water, stirring well, and then adding 1.01 mol of sodium bromide; S12. slowly dropping in 10% sodium chlorite solution (effective chlorine content of 128.2.0 sodium bromide equivalents) over a period of 1-2 hours at room temperature and stirring; and continuing the reaction for 4-8 hours after dropping. Sodium solution (effective chlorine content of 128.2.0 sodium bromide equivalent), after dropping, continue to stir the reaction at room temperature for 4-8 hours. The conversion of 2-bromo-4-tert-butylphenol prepared by this method was more than 99%, the yield was 97% and the purity of the product was 98.3%. | | References | [1] Journal of the American Chemical Society, 1982, vol. 104, # 5, p. 1362 - 1368
[2] Chemistry - A European Journal, 2012, vol. 18, # 11, p. 3286 - 3291
[3] Patent: US2014/135320, 2014, A1. Location in patent: Page/Page column 0219
[4] Patent: US2014/135360, 2014, A1. Location in patent: Paragraph 0147
[5] Tetrahedron Asymmetry, 1999, vol. 10, # 3, p. 411 - 427 |
| | 2-Bromo-4-tert-butylphenol Preparation Products And Raw materials |
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